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Ch.8 - Basic Concepts of Chemical Bonding
Chapter 8, Problem 79a

Consider the lattice energies of the following Group 2A compounds: BeH2, 3205 kJ/mol; MgH2, 2791 kJ/mol; CaH2, 2410 kJ/mol; SrH2, 2250 kJ/mol; BaH2, 2121 kJ/mol. (a) What is the oxidation number of H in these compounds?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Oxidation Number

The oxidation number, or oxidation state, is a theoretical charge assigned to an atom in a compound based on the assumption that electrons are completely transferred. In compounds, hydrogen typically has an oxidation number of +1 when bonded to nonmetals and -1 when bonded to metals. Understanding this concept is crucial for determining the oxidation states of elements in various compounds.
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Group 2A Elements

Group 2A elements, also known as alkaline earth metals, include beryllium (Be), magnesium (Mg), calcium (Ca), strontium (Sr), and barium (Ba). These elements typically have an oxidation state of +2 in their compounds due to the loss of their two outermost electrons. Recognizing the behavior of these metals helps in predicting the oxidation states of hydrogen in their hydrides.
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Hydrides

Hydrides are compounds formed between hydrogen and other elements, where hydrogen can exhibit different oxidation states. In the case of alkaline earth metal hydrides, hydrogen is usually in the -1 oxidation state when bonded to metals. This understanding is essential for analyzing the oxidation states in the given Group 2A hydrides.
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Related Practice
Textbook Question

Some chemists believe that satisfaction of the octet rule should be the top criterion for choosing the dominant Lewis structure of a molecule or ion. Other chemists believe that achieving the best formal charges should be the top criterion. Consider the dihydrogen phosphate ion, H2PO4-, in which the H atoms are bonded to O atoms. (b) What is the predicted dominant Lewis structure if achieving the best formal charges is the top criterion?

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Textbook Question

State whether each of these statements is true or false. (e) The longer the bond, the more energy is stored chemical bonds.

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Textbook Question
Draw the Lewis structure for NO+ . Is the nitrogen– oxygen bond in NO+ longer, shorter, or the same length as the nitrogen–oxygen bond in NO? Explain. Draw the Lewis structure for NO+ .
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Textbook Question

The ionic compound CaO crystallizes with the same structure as sodium chloride (Figure 8.3). (a) In this structure, how many O2- are in contact with each Ca2+ ion (Hint: Remember the pattern of ions shown in Figure 8.3 repeats over and over again in all three directions.)

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Textbook Question

Construct a Born–Haber cycle for the formation of the hypothetical compound NaCl2, where the sodium ion has a 2+ charge (the second ionization energy for sodium is given in Table 7.2). (a) How large would the lattice energy need to be for the formation of NaCl2 to be exothermic?

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Textbook Question

Consider the collection of nonmetallic elements O, P, Te, I, and B. (a) Which two would form the most polar single bond?

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