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Biological Macromolecules and Carbohydrates

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  • What are biological macromolecules?

    Biological macromolecules are large, complex organic molecules essential for life, with unique properties arising from their atomic arrangement and functional groups.

  • Name the four major classes of biological macromolecules.

    The four major classes are carbohydrates, proteins, nucleic acids, and lipids.

  • Which biological macromolecules are polymers?

    Carbohydrates, proteins, and nucleic acids are polymers; lipids are not polymers.

  • Define polymer and monomer.

    A polymer is a large molecule made of repeating subunits called monomers linked by covalent bonds.

  • What is a dehydration reaction?

    A dehydration reaction synthesizes polymers by removing a water molecule to form a new covalent bond between monomers.

  • What happens during hydrolysis?

    Hydrolysis breaks polymers into monomers by adding a water molecule, breaking the covalent bond.

  • What are monosaccharides?

    Monosaccharides are the simplest carbohydrates, single sugar molecules like glucose, often with formula multiples of (CH2O).

  • What are polysaccharides?

    Polysaccharides are polymers of many sugar monomers linked together, such as starch and cellulose.

  • What are the two main biological functions of carbohydrates?

    Carbohydrates store energy and provide structural support to cells and organisms.

  • How do 5- and 6-carbon sugars exist in solution?

    They exist in dynamic equilibrium between linear and ring forms, with ring forms favored in cells.

  • What is a glycosidic linkage?

    A glycosidic linkage is a covalent bond formed between two monosaccharides during dehydration to make disaccharides or polysaccharides.

  • What is starch and its role in plants?

    Starch is a plant storage polysaccharide made of glucose monomers, stored as granules for energy reserves.

  • What is glycogen and its role in animals?

    Glycogen is a highly branched glucose polymer used by animals for rapid energy release, stored mainly in liver and muscle cells.

  • What distinguishes α and β glucose?

    They differ in the orientation of the hydroxyl group on carbon 1: α has it below the ring, β has it above.

  • How do amylose and cellulose differ structurally?

    Amylose has α-1,4 glycosidic linkages forming a helical structure; cellulose has β-1,4 linkages forming straight, rigid fibers.

  • Why is cellulose used for structural support in plants?

    Cellulose forms strong fibers via hydrogen bonds between β-glucose chains, making plant cell walls tough and rigid.

  • What is chitin and its biological role?

    Chitin is a polysaccharide similar to cellulose but with nitrogen-containing groups, providing structure in fungal cell walls and arthropod exoskeletons.

  • Why do glucose molecules dissolve in water?

    Glucose has many polar hydroxyl (-OH) groups that form hydrogen bonds with water, making it soluble.

  • What is the significance of enzymes in polymer synthesis and breakdown?

    Enzymes speed up dehydration and hydrolysis reactions, facilitating polymer synthesis and breakdown in cells.

  • What does the term 'poly-' and 'mono-' mean in polymer chemistry?

    Poly- means many; mono- means one, referring to many monomers forming a polymer.