General Biology: Structure and Function of Large Biological Molecules
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A polymer is a long molecule made up of many similar or identical building blocks called monomers, connected by covalent bonds.
Monomers are small molecules that serve as the building blocks of polymers.
A dehydration reaction connects monomers by removing a water molecule, forming a covalent bond and requiring energy.
Hydrolysis breaks covalent bonds in polymers by adding water, releasing energy and separating monomers.
Carbohydrates include sugars and their polymers, serving as fuel and building material.
Monosaccharides are simple sugars and the simplest carbohydrates, e.g., glucose.
Disaccharides form when two monosaccharides join by a glycosidic linkage via dehydration.
Polysaccharides are polymers of many monosaccharides joined by glycosidic linkages, functioning in storage or structure.
Monosaccharides typically have molecular formulas that are multiples of \(CH_2O\).
Monosaccharides are classified as aldoses (aldehyde group) or ketoses (ketone group) based on carbonyl location.
Monosaccharides are classified by carbon number: trioses (3), pentoses (5), hexoses (6).
Isomers arise from different spatial arrangements around asymmetric carbons in sugars with the same formula.
Glucose is a major nutrient used for cellular work and energy extraction via cellular respiration.
Starch is a plant storage polysaccharide made of glucose monomers connected mainly by 1–4 glycosidic linkages.
Amylose is unbranched starch; amylopectin is branched starch.
Glycogen is an extensively branched animal storage polysaccharide similar to amylopectin, stored in liver and muscles.
Cellulose is a structural polysaccharide in plant cell walls made of β-glucose monomers with 1–4 linkages, forming straight chains.
Humans lack enzymes to hydrolyze β-glycosidic linkages in cellulose, unlike α-linkages in starch.
Chitin is a nitrogen-containing structural polysaccharide in arthropod exoskeletons and fungal cell walls.
Dehydration synthesis removes water between two monosaccharides, forming a glycosidic bond linking them.