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General Chemistry: Atomic Structure and Light

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  • Law of Multiple Proportions

    When two elements form different compounds, the masses of one element that combine with a fixed mass of the other are in a whole number ratio.

  • Example of Law of Multiple Proportions

    Carbon monoxide and carbon dioxide both contain C and O. The mass ratio of oxygen to carbon in CO2 is 2.67:1, and in CO it is 1.33:1, a simple whole number ratio.

  • J.J. Thomson's Cathode Ray Experiment

    Discovered cathode rays are negatively charged particles (electrons) that travel in straight lines and are independent of the cathode.

  • Dalton's Atomic Theory Key Points

    1. Elements are made of atoms.
    2. Atoms of an element are identical.
    3. Atoms combine in whole number ratios.
    4. Atoms cannot change into other elements.

  • Nuclear Theory of the Atom

    1. Most mass and positive charge are in the nucleus.
    2. Most volume is empty space with electrons.
    3. In neutral atoms, positive and negative charges are equal.

  • Neutrons

    Neutral particles in the nucleus with mass similar to protons; explain atomic mass differences in isotopes.

  • Atomic Number (Z)

    The number of protons in the nucleus; defines the element.

  • Mass Number (A)

    The total number of protons and neutrons in an atom's nucleus.

  • Isotopes

    Atoms of the same element with different numbers of neutrons but the same number of protons.

  • Ions

    Charged atoms formed by losing or gaining electrons; cations are positive, anions are negative.

  • Atomic Mass on the Periodic Table

    Weighted average mass of an element's naturally occurring isotopes.

  • Molar Mass

    Mass of one mole of a substance, equal to the atomic or molecular mass in grams per mole.

  • Avogadro's Number

    Number of particles in one mole: \(6.022 \times 10^{23}\).

  • Wave-Particle Duality

    Electrons and light exhibit both wave and particle properties.

  • Speed of Light in Vacuum

    Constant speed of light: \(3.00 \times 10^{8} \text{ m/s}\).

  • Wavelength (λ)

    Distance between successive crests or troughs of a wave; determines light color.

  • Frequency (ν)

    Number of waves passing a point per second; unit is hertz (Hz).

  • Relationship Between Wavelength and Frequency

    Wavelength and frequency are inversely proportional for waves traveling at constant speed.

  • Photoelectric Effect

    Emission of electrons from a metal surface when light shines on it, explained by photons with energy \(E=hv\).

  • Einstein's Quantum Theory of Light

    Light consists of photons; energy of a photon is \(E=hv\), where h is Planck's constant.

  • Bohr Model of the Atom

    Electrons orbit the nucleus in fixed energy levels; emit photons when jumping to lower energy orbits.

  • De Broglie Hypothesis

    Particles like electrons have wave properties; wave nature is significant for very small particles.

  • Heisenberg Uncertainty Principle

    It is impossible to know both the exact position and velocity of an electron simultaneously.

  • Determinacy vs Indeterminacy in Electron Behavior

    Classical physics predicts definite paths (determinacy), but electron paths are probabilistic (indeterminacy).

  • Schrödinger's Equation

    Calculates the probability of finding an electron with a certain energy at a specific location in an atom.

  • Quantum Numbers

    Set of integers (n, l, ml, ms) that describe electron energy, orbital shape, orientation, and spin.