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Ch.3 - Mass Relationships in Chemical Reactions
McMurry - Chemistry 8th Edition
McMurry8th EditionChemistryISBN: 9781292336145Non è quello che usi tu?Cambia libro di testo
Capitolo 3, Problema 83

If 3.42 g of K2PtCl4 and 1.61 g of NH3 give 2.08 g of cispla-tin (Problem 3.81), what is the percent yield of the reaction?

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1
Identify the balanced chemical equation for the reaction. The reaction involves K2PtCl4 and NH3 to form cisplatin (Pt(NH3)2Cl2).
Calculate the theoretical yield of cisplatin. First, determine the molar masses of K2PtCl4, NH3, and cisplatin (Pt(NH3)2Cl2).
Convert the given masses of K2PtCl4 and NH3 to moles using their respective molar masses.
Determine the limiting reactant by comparing the mole ratio of the reactants to the stoichiometry of the balanced equation.
Use the moles of the limiting reactant to calculate the theoretical yield of cisplatin in grams, then calculate the percent yield using the formula: \( \text{Percent Yield} = \left( \frac{\text{Actual Yield}}{\text{Theoretical Yield}} \right) \times 100 \).

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Percent Yield

Percent yield is a measure of the efficiency of a chemical reaction, calculated by comparing the actual yield of a product to the theoretical yield. It is expressed as a percentage and is determined using the formula: (actual yield / theoretical yield) x 100. A high percent yield indicates a more efficient reaction, while a low percent yield may suggest incomplete reactions or losses during the process.
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Percent Yield in Reactions

Stoichiometry

Stoichiometry involves the calculation of reactants and products in chemical reactions based on the balanced chemical equation. It allows chemists to predict the amounts of substances consumed and produced in a reaction. Understanding stoichiometry is essential for determining the theoretical yield, which is the maximum amount of product that can be formed from given amounts of reactants.
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Stoichiometry Concept

Limiting Reactant

The limiting reactant is the substance that is completely consumed first in a chemical reaction, thus determining the maximum amount of product that can be formed. Identifying the limiting reactant is crucial for calculating the theoretical yield, as it dictates how much of the product can be produced based on the initial quantities of reactants. The reactant in excess will remain after the reaction is complete.
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Pratica correlata
Domanda del libro di testo

The reaction of tungsten hexachloride (WCl6) with bismuth gives hexatungsten dodecachloride (W6Cl12).

WCl6 + Bi → W6Cl12 + BiCl3 Unbalanced

(b) How many grams of bismuth react with 150.0 g of WCl6?

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Domanda del libro di testo
Acetic acid (CH3CO2H) reacts with isopentyl alcohol (C5H12O) to yield isopentyl acetate (C7H14O2), a fragrant substance with the odor of bananas. If the yield from the reaction of acetic acid with isopentyl alcohol is 45%, how many grams of isopentyl acetate are formed from 3.58 g of acetic acid and 4.75 g of isopentyl alcohol? The reaction is CH3CO2H + C5H12O ---> C7H14O2 + H2O
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Domanda del libro di testo

The reaction of tungsten hexachloride (WCl6) with bismuth gives hexatungsten dodecachloride (W6Cl12).

WCl6 + Bi → W6Cl12 + BiCl3 Unbalanced

(c) When 228 g of WCl6 react with 175 g of Bi, how much W6Cl12 is formed based on the limiting reactant?

517
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Domanda del libro di testo
Cisplatin [Pt(NH3)2Cl2], a compound used in cancer treat-ment, is prepared by reaction of ammonia with potassium tetrachloroplatinate: K2PtCl4 + 2 NH3 ----> 2 KCl + Pt(NH3)2Cl2 How many grams of cisplatin are formed from 55.8 g of K2PtCl4 and 35.6 g of NH3 if the reaction takes place in 95% yield based on the limiting reactant?
1709
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Domanda del libro di testo

The reaction of tungsten hexachloride (WCl6) with bismuth gives hexatungsten dodecachloride (W6Cl12).

WCl6 + Bi → W6Cl12 + BiCl3 Unbalanced

(a) Balance the equation.

765
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Domanda del libro di testo
If 1.87 g of acetic acid (CH3COOH) reacts with 2.31 g of isopentyl alcohol (C5H12O) to give 2.96 g of isopentyl acetate (C7H14O2), what is the percent yield of the reaction?
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