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GOB Chemistry: Reactions of Molecules

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  • Law of conservation of matter

    Atoms are not created or destroyed in chemical reactions; the total number of atoms is conserved.

  • Balanced chemical reaction

    A chemical equation where the number of atoms of each element is the same on both sides, achieved by adjusting coefficients.

  • Mole (mol)

    A unit representing 6.022 x 1023 atoms or molecules, also called Avogadro's number.

  • Stoichiometry

    Use of reaction coefficients to calculate amounts of reactants and products, usually in moles, based on balanced equations.

  • Oxidation

    Loss of electrons or increase in oxidation number; often involves gaining bonds to oxygen or losing bonds to hydrogen.

  • Reduction

    Gain of electrons or decrease in oxidation number; often involves losing bonds to oxygen or gaining bonds to hydrogen.

  • Redox reaction

    A reaction involving simultaneous oxidation and reduction; electrons lost by one species are gained by another.

  • Oxidation number rules

    Ox # of uncombined atom = 0; monatomic ion = charge; Group IA = +1; Group IIA = +2; H = +1; O = -2 (except peroxides); sum equals compound charge.

  • Enthalpy (ΔH)

    Thermal energy released or absorbed during a reaction, measured per mole of reaction coefficients.

  • Exothermic reaction

    Reaction that releases heat to surroundings; has a negative ΔH.

  • Endothermic reaction

    Reaction that absorbs heat from surroundings; has a positive ΔH.

  • Entropy (ΔS)

    Measure of disorder in a system; increases with more disorder and higher temperature.

  • Spontaneous reaction

    A reaction that proceeds without external input; characterized by negative free energy change (ΔG).

  • Free energy (ΔG)

    Energy available to do work; calculated as \(\Delta G = \Delta H - T\Delta S\).

  • Exergonic process

    Reaction that releases free energy; has negative ΔG and is spontaneous.

  • Endergonic process

    Reaction that requires free energy input; has positive ΔG and is non-spontaneous.

  • Activation energy (Eact)

    Minimum energy required to start a reaction; determines reaction rate.

  • Reaction rate

    Speed of a reaction measured by change in concentration of reactants or products over time.

  • Factors increasing reaction rate

    Higher temperature, higher concentration, and presence of a catalyst increase reaction rate.

  • Catalyst

    Substance that lowers activation energy and speeds up reaction rate without being consumed.

  • Chemical equilibrium

    State where forward and reverse reaction rates are equal; concentrations remain constant.

  • Equilibrium constant (Keq)

    Ratio of product concentrations to reactant concentrations at equilibrium; indicates reaction direction.

  • Le Châtelier’s Principle

    When a system at equilibrium is stressed, it shifts to relieve the stress by favoring forward or reverse reaction.

  • Effect of temperature on equilibrium

    Increasing temperature favors endothermic direction; decreasing temperature favors exothermic direction.

  • Effect of concentration on equilibrium

    Adding reactants or removing products shifts equilibrium forward; adding products or removing reactants shifts it backward.

  • Effect of catalyst on equilibrium

    Catalysts speed up reaching equilibrium but do not change the equilibrium constant or position.