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Potentiometry definitions
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Potentiometry
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Potentiometry
Analytical technique measuring voltage between electrodes without current to determine solution composition.
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Termini in questo insieme (15)
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Potentiometry
Analytical technique measuring voltage between electrodes without current to determine solution composition.
Electrochemical Cell
System consisting of two electrodes and solutions, enabling measurement of voltage differences for analysis.
Indicator Electrode
Component interacting with the analyte, reflecting changes in solution composition through its potential.
Reference Electrode
Electrode maintaining constant potential, providing a stable comparison for voltage measurements.
Analyte
Substance in solution whose concentration or composition is determined by voltage measurement.
Cell Potential
Measured voltage difference between indicator and reference electrodes, including any junction effects.
Junction Potential
Voltage arising at the interface of two electrolyte solutions, minimized by using similar ion sizes.
Salt Bridge
Device containing neutral salts, connecting half-cells and minimizing voltage imbalances between them.
Potassium Chloride
Preferred salt in bridges due to similar ion sizes, effectively reducing unwanted voltage differences.
Nernst Equation
Mathematical relationship linking electrode potential to analyte concentration and redox state.
Half Reaction
Process describing electron transfer at each electrode, crucial for understanding cell operation.
Anode
Electrode where oxidation occurs, often associated with the reference side in potentiometric cells.
Cathode
Electrode where reduction occurs, typically connected to the indicator electrode in analysis.
Platinum Electrode
Inert conductor used when no solid analyte forms, ensuring accurate potential measurement.
Precipitate
Solid formed during electrode reactions, such as silver chloride, indicating specific chemical changes.