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General Chemistry: Atoms and Elements

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  • What is an atom?

    An atom is the smallest identifiable unit of an element that retains the element's properties.

  • What does the word 'atom' mean?

    The word atom comes from the Greek atomos, meaning indivisible.

  • What did Robert Brown observe in Brownian motion?

    He observed that particles suspended in water were in continuous motion, caused by collisions with atoms or molecules.

  • What did Einstein and Perrin contribute to atomic theory?

    Einstein developed a theory explaining Brownian motion; Perrin experimentally confirmed it, supporting the particulate nature of matter.

  • What are the three key laws that led to atomic theory?

    The law of conservation of mass, law of definite proportions, and law of multiple proportions.

  • State the law of conservation of mass.

    In a chemical reaction, matter is neither created nor destroyed; total mass remains constant.

  • What does the law of definite proportions state?

    All samples of a given compound have the same proportions of their constituent elements by mass.

  • Explain the law of multiple proportions.

    When two elements form different compounds, the masses of one element that combine with a fixed mass of the other are in ratios of small whole numbers.

  • What are the main points of Dalton's atomic theory?

    Atoms are tiny, indestructible particles; atoms of an element are identical; atoms combine in whole-number ratios; atoms rearrange in reactions but do not change into other atoms.

  • What did J. J. Thomson discover?

    He discovered the electron, a negatively charged, low-mass particle within atoms, using cathode ray experiments.

  • What was Millikan's oil drop experiment about?

    It measured the charge of a single electron by balancing gravitational and electric forces on charged oil drops.

  • Describe Rutherford's gold foil experiment findings.

    Most alpha particles passed through gold foil, but some were deflected or bounced back, indicating a small, dense, positively charged nucleus.

  • What is the nuclear theory of the atom?

    Most mass and positive charge are in a small nucleus; electrons occupy empty space around it; atoms are electrically neutral.

  • What are neutrons?

    Neutrons are neutral particles in the nucleus with mass similar to protons but no charge.

  • What defines an element's identity?

    The number of protons in its nucleus, called the atomic number (Z).

  • What are isotopes?

    Atoms of the same element with the same number of protons but different numbers of neutrons.

  • How is the mass number (A) defined?

    Mass number = number of protons + number of neutrons in an atom.

  • What are ions?

    Charged atoms formed by loss or gain of electrons; cations are positive, anions are negative.

  • What is the periodic law?

    When elements are arranged by increasing atomic number, their properties recur periodically.

  • What are the main classifications of elements in the periodic table?

    Metals, nonmetals, and metalloids.

  • What are the properties of metals?

    Good conductors, malleable, ductile, shiny, tend to lose electrons in reactions.

  • What are the properties of nonmetals?

    Poor conductors, not malleable or ductile, tend to gain electrons in reactions.

  • What are metalloids?

    Elements with mixed properties between metals and nonmetals, often semiconductors.

  • What is a mole?

    A unit representing Avogadro's number (\(6.022\times10^{23}\)) of particles.

  • How is molar mass related to atomic mass?

    Molar mass (g/mol) is numerically equal to the atomic mass (amu) of an element.

  • How do you calculate atomic mass from isotopes?

    Atomic mass = sum of (isotope mass × fractional natural abundance) for all isotopes.