General Chemistry: Polyatomic Ions
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A polyatomic ion is a charged species composed of two or more atoms covalently bonded that act as a single ion.
Nitrate is the polyatomic ion with formula \(\mathrm{NO_3^-}\).
The sulfate ion, \(\mathrm{SO_4^{2-}}\), has a charge of 2-.
The ammonium ion is \(\mathrm{NH_4^+}\) with a charge of 1+.
Hydroxide is the polyatomic ion with formula \(\mathrm{OH^-}\).
Polyatomic ions with oxygen are called oxyanions. The one with fewer oxygens ends with -ite, and the one with more oxygens ends with -ate.
Carbonate ion has the formula \(\mathrm{CO_3^{2-}}\).
The phosphate ion, \(\mathrm{PO_4^{3-}}\), has a charge of 3-.
Perchlorate is the polyatomic ion with formula \(\mathrm{ClO_4^-}\).
Nitrate is \(\mathrm{NO_3^-}\) and nitrite is \(\mathrm{NO_2^-}\). Nitrate has one more oxygen.
Cyanide is the polyatomic ion with formula \(\mathrm{CN^-}\).
Polyatomic ions act as a single charged unit in ionic compounds and are named as such in the compound's name.
Acetate ion has the formula \(\mathrm{C_2H_3O_2^-}\) or \(\mathrm{CH_3COO^-}\) with a charge of 1-.
Hydrogen carbonate (or bicarbonate) ion is \(\mathrm{HCO_3^-}\).
The dichromate ion, \(\mathrm{Cr_2O_7^{2-}}\), has a charge of 2-.
Permanganate is the polyatomic ion with formula \(\mathrm{MnO_4^-}\).
Chlorite ion has the formula \(\mathrm{ClO_2^-}\).
Thiosulfate ion is \(\mathrm{S_2O_3^{2-}}\) with a charge of 2-.
Polyatomic ions appear as groups of atoms in parentheses with a charge, e.g., \((\mathrm{SO_4})^{2-}\).
Hypochlorite ion has the formula \(\mathrm{ClO^-}\).