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Ch.5 - Thermochemistry
Brown - Chemistry: The Central Science 14th Edition
Brown14th EditionChemistry: The Central ScienceISBN: 9780134414232Non è quello che usi tu?Cambia libro di testo
Capitolo 5, Problema 59a

Under constant-volume conditions, the heat of combustion of benzoic acid (C6H5O6) is 15.57 kJ/g. A 3.500-g sample of sucrose is burned in a bomb calorimeter. The temperature of the calorimeter increases from 20.94 to 24.72 °C. (a) What is the total heat capacity of the calorimeter?

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Identify the known values: the heat of combustion of benzoic acid is 15.57 kJ/g, the mass of the sucrose sample is 3.500 g, and the temperature change (\(\Delta T\)) is from 20.94 °C to 24.72 °C.
Calculate the total heat released by the combustion of the sucrose sample using the formula \( q = m \times \Delta H \), where \( m \) is the mass of the sucrose and \( \Delta H \) is the heat of combustion per gram.
Determine the temperature change \( \Delta T \) of the calorimeter by subtracting the initial temperature from the final temperature.
Use the formula for heat capacity \( C = \frac{q}{\Delta T} \) to find the total heat capacity of the calorimeter, where \( q \) is the heat released and \( \Delta T \) is the temperature change.
Substitute the values obtained from the previous steps into the formula to calculate the total heat capacity of the calorimeter.

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Heat Capacity

Heat capacity is the amount of heat energy required to raise the temperature of a substance by one degree Celsius. In calorimetry, it is crucial for determining how much heat is absorbed or released by the calorimeter during a reaction. The total heat capacity of a calorimeter can be calculated using the formula C = q/ΔT, where q is the heat exchanged and ΔT is the change in temperature.
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Calorimetry

Calorimetry is the science of measuring the heat of chemical reactions or physical changes. In a bomb calorimeter, the heat released from a combustion reaction is absorbed by the calorimeter and the surrounding water, leading to a measurable temperature change. This technique allows for the determination of the energy content of fuels and other substances.
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Constant-Volume Calorimetry

Combustion Reaction

A combustion reaction is a chemical process in which a substance reacts rapidly with oxygen, producing heat and light. In the context of calorimetry, the heat released during the combustion of a sample, such as sucrose, is measured to determine its energy content. The heat of combustion is typically expressed in kJ/g, indicating the energy released per gram of the substance burned.
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Combustion Apparatus
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