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Ch.5 - Thermochemistry
Brown - Chemistry: The Central Science 15th Edition
Brown15th EditionChemistry: The Central ScienceISBN: 9780137542970Non è quello che usi tu?Cambia libro di testo
Capitolo 5, Problema 115

Use average bond enthalpies from Table 5.4 to estimate Δ𝐻 for the following gas-phase reaction of ethylene, (C2H4), oxygen, and hydrogen to form ethylene glycol (C2H6O2), which is the principal component of automotive antifreeze:

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Identify the bonds broken and formed in the reaction. For ethylene (C2H4), oxygen (O2), and hydrogen (H2) reacting to form ethylene glycol (C2H6O2), list all the bonds in the reactants and products.
Use the average bond enthalpies from Table 5.4 to find the energy required to break each type of bond in the reactants. Sum these values to get the total energy required to break all the bonds in the reactants.
Similarly, use the average bond enthalpies to find the energy released when new bonds are formed in the products. Sum these values to get the total energy released in forming the products.
Calculate the change in enthalpy (ΔH) for the reaction using the formula: ΔH = (Total energy required to break bonds) - (Total energy released in forming bonds).
Interpret the sign of ΔH to determine whether the reaction is endothermic (positive ΔH) or exothermic (negative ΔH).

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Bond Enthalpy

Bond enthalpy, or bond dissociation energy, is the amount of energy required to break one mole of a specific type of bond in a gaseous substance. It is a measure of bond strength and varies depending on the type of bond and the surrounding atoms. Average bond enthalpies are often used in calculations to estimate the energy changes during chemical reactions.
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Enthalpy of Formation

Enthalpy Change (ΔH)

The enthalpy change (ΔH) of a reaction is the difference in total energy between the products and reactants. It indicates whether a reaction is exothermic (releases heat, ΔH < 0) or endothermic (absorbs heat, ΔH > 0). In the context of bond enthalpies, ΔH can be estimated by subtracting the total bond enthalpies of the products from those of the reactants.
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Enthalpy of Formation

Gas-Phase Reactions

Gas-phase reactions occur when reactants and products are in the gaseous state, allowing for simpler calculations of energy changes since intermolecular forces are minimal. In these reactions, the average bond enthalpies can be directly applied to estimate ΔH, as the molecules are not influenced by solvent interactions or other phases.
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Phase Changes in Diagrams
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The Sun supplies about 1.0 kilowatt of energy for each square meter of surface area (1.0 kW/m2, where a watt=1 J/s). Plants produce the equivalent of about 0.20 g of sucrose (C12H22O11) per hour per square meter. Assuming that the sucrose is produced as follows, calculate the percentage of sunlight used to produce sucrose. 12 CO2(g) + 11 H2O(l) → C12H22O11 + 12 O2(g) H = 5645 kJ

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Depending on their specific usage, fuels are judged in part on energy released per unit volume and energy released per unit mass. Three prospective fuels are listed in the following table, along with their densities and molar enthalpies of combustion.

a. Rank the three fuels according to their enthalpy produced per gram.

b. Rank them according to their enthalpy produced per cm3:

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(b) Assuming that there is an uncertainty of 0.002 °C in each temperature reading and that the masses of samples are measured to 0.001 g, what is the estimated uncertainty in the value calculated for the heat of combustion per mole of caffeine?

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A coffee-cup calorimeter of the type shown in Figure 5.18 contains 150.0 g of water at 25.1°C A 121.0-g block of copper metal is heated to 100.4°C by putting it in a beaker of boiling water. The specific heat of Cu(s) is 0.385 J/g-K The Cu is added to the calorimeter, and after a time the contents of the cup reach a constant temperature of 30.1°C (d) What would be the final temperature of the system if all the heat lost by the copper block were absorbed by the water in the calorimeter?

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