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Ch.12 - Solids and Solid-State Materials
McMurry - Chemistry 8th Edition
McMurry8th EditionChemistryISBN: 9781292336145Non è quello che usi tu?Cambia libro di testo
Capitolo 12, Problema 22c

The following diagrams show the electron populations of the bands of MO energy levels for four different materials:
Diagrams showing MO energy levels for four materials and their conductivity changes with temperature.
. (c) Tell whether the conductivity of each material increases or decreases when the temperature increases.

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Identify the type of material based on the electron population in the bands: insulator, semiconductor, or conductor.
For each material, observe the distribution of electrons in the valence band (red) and conduction band (blue).
Recall that in conductors, the conductivity decreases with increasing temperature due to increased electron scattering.
For semiconductors, the conductivity increases with increasing temperature as more electrons gain enough energy to jump from the valence band to the conduction band.
For insulators, the conductivity remains very low and does not significantly change with temperature.

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Molecular Orbital Theory

Molecular Orbital (MO) Theory describes the behavior of electrons in molecules by combining atomic orbitals to form molecular orbitals. These orbitals can be filled with electrons and are categorized as bonding or antibonding. The arrangement of these orbitals influences the electrical properties of materials, including their conductivity.
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Molecular Orbital Theory

Conductivity and Temperature Relationship

The conductivity of materials is often affected by temperature changes. In semiconductors, increasing temperature typically provides energy to electrons, allowing them to move from the valence band to the conduction band, thus increasing conductivity. Conversely, in some metals, increased temperature can lead to increased lattice vibrations, which may decrease conductivity.
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Temperature vs Heat

Band Gap

The band gap is the energy difference between the valence band and the conduction band in a material. Materials with a small band gap, like semiconductors, can have their conductivity significantly affected by temperature, as thermal energy can promote electrons across the gap. In contrast, materials with a large band gap are generally insulators and show little change in conductivity with temperature.
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Intepreting the Band of Stability