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Ch.13 - Solutions & Their Properties
McMurry - Chemistry 8th Edition
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Capitolo 13, Problema 47

Predict whether the solubility of butane, C4H10, is greater in water or benzene, C6H6.

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Step 1: Understand the nature of butane (C4H10). Butane is a nonpolar hydrocarbon molecule.
Step 2: Consider the nature of water. Water is a polar solvent with strong hydrogen bonding capabilities.
Step 3: Consider the nature of benzene (C6H6). Benzene is a nonpolar solvent.
Step 4: Apply the principle 'like dissolves like', which suggests that nonpolar solutes are more soluble in nonpolar solvents.
Step 5: Conclude that butane, being nonpolar, is more likely to be soluble in benzene, a nonpolar solvent, than in water, a polar solvent.

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Polarity

Polarity refers to the distribution of electrical charge over the atoms in a molecule. Polar molecules, like water, have a significant difference in electronegativity between their atoms, leading to partial positive and negative charges. Nonpolar molecules, such as butane, have an even distribution of charge. Understanding polarity is crucial for predicting solubility, as 'like dissolves like' means polar substances dissolve well in polar solvents, while nonpolar substances dissolve better in nonpolar solvents.
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Hydrophobic and Hydrophilic Interactions

Hydrophobic interactions occur between nonpolar molecules that do not interact favorably with water, while hydrophilic interactions occur between polar molecules that can form hydrogen bonds with water. Butane, being a nonpolar hydrocarbon, is hydrophobic and will not dissolve well in water. In contrast, benzene is also nonpolar, making it a more suitable solvent for butane due to similar intermolecular forces.
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Solubility Principles

Solubility is the ability of a solute to dissolve in a solvent at a given temperature and pressure. Factors influencing solubility include temperature, pressure, and the nature of the solute and solvent. For butane, its solubility is expected to be higher in benzene than in water due to the nonpolar nature of both butane and benzene, which allows for favorable interactions compared to the polar nature of water.
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