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Ch.19 - Electrochemistry
McMurry - Chemistry 8th Edition
McMurry8th EditionChemistryISBN: 9781292336145Non è quello che usi tu?Cambia libro di testo
Capitolo 19, Problema 1

Which of the following unbalanced half-reactions is correctly labeled as an oxidation or reduction? (a) NO3- (aq) → NO(g); reduction (b) Zn(s) → Zn2+(aq); reduction (c) ClO3-(aq) → Cl2(g); oxidation (d) Br-(aq) → Br2(l); reduction

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1
Identify the process of oxidation and reduction: Oxidation involves the loss of electrons, while reduction involves the gain of electrons.
Examine each half-reaction to determine if it involves oxidation or reduction by checking the change in oxidation states of the elements involved.
For option (a) NO_3^- (aq) → NO(g), determine the change in oxidation state of nitrogen to see if it gains or loses electrons.
For option (b) Zn(s) → Zn^{2+}(aq), check if zinc loses electrons, indicating oxidation.
For option (c) ClO_3^-(aq) → Cl_2(g) and option (d) Br^-(aq) → Br_2(l), analyze the changes in oxidation states of chlorine and bromine, respectively, to identify if they are oxidized or reduced.

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Oxidation and Reduction

Oxidation and reduction are chemical processes that involve the transfer of electrons between species. Oxidation refers to the loss of electrons, resulting in an increase in oxidation state, while reduction involves the gain of electrons, leading to a decrease in oxidation state. Understanding these processes is crucial for identifying half-reactions in redox reactions.
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Oxidation and Reduction Reactions

Half-Reactions

Half-reactions are equations that show either the oxidation or reduction process separately. They are used to balance redox reactions by clearly indicating the species that are oxidized and reduced. Each half-reaction must be balanced for both mass and charge, which is essential for determining the correct labeling of oxidation and reduction.
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First-Order Half-Life

Oxidation States

Oxidation states (or numbers) are assigned to atoms in a compound to indicate their degree of oxidation or reduction. These states help in tracking electron transfer during chemical reactions. By analyzing the changes in oxidation states of the elements involved, one can determine whether a reaction is an oxidation or reduction process.
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Oxidation Numbers