Skip to main content
Ch.22 - The Main Group Elements
McMurry - Chemistry 8th Edition
McMurry8th EditionChemistryISBN: 9781292336145Non è quello che usi tu?Cambia libro di testo
Tutti i libri di testoMcMurry 8th EditionCh.22 - The Main Group ElementsProblema 22.47
Capitolo 22, Problema 22.47

GeCl4 reacts with Cl- to give GeCl62-, but CCl4 does not react with excess Cl-. Explain.

Guida verificata passo dopo passo
1
Identify the central atoms in GeCl_4 and CCl_4, which are Ge (Germanium) and C (Carbon), respectively.
Consider the electronic configuration and oxidation states of Ge and C. Ge can expand its octet due to available d-orbitals, while C cannot because it lacks d-orbitals.
Understand that GeCl_4 can accept additional Cl^- ions to form GeCl_6^{2-} because Ge can accommodate more than 8 electrons in its valence shell.
Recognize that CCl_4 does not react with Cl^- because carbon cannot expand its octet beyond 8 electrons, as it only has s and p orbitals available.
Conclude that the ability of Ge to expand its octet allows GeCl_4 to react with Cl^-, while the lack of d-orbitals in carbon prevents CCl_4 from doing the same.

Risposta video verificata per un problema simile:

Questa soluzione video è stata consigliata dai nostri tutor come utile per risolvere questo problema.

Concetti chiave

Ecco i concetti essenziali che devi comprendere per rispondere correttamente alla domanda.

Coordination Chemistry

Coordination chemistry involves the study of complex compounds formed between metal ions and ligands. In this context, GeCl<sub>4</sub> acts as a Lewis acid, accepting electron pairs from Cl<sup>-</sup> ligands to form the stable complex GeCl<sub>6</sub><sup>2-</sup>. Understanding how ligands interact with metal centers is crucial for explaining the reactivity of these compounds.
Video consigliato:
Percorso guidato
00:27
Coordination Numbers

Lewis Acids and Bases

Lewis acids are substances that can accept an electron pair, while Lewis bases donate an electron pair. GeCl<sub>4</sub> is a Lewis acid that can react with Cl<sup>-</sup> ions, whereas CCl<sub>4</sub> is a neutral molecule and does not exhibit Lewis acid behavior. This distinction is key to understanding why GeCl<sub>4</sub> reacts while CCl<sub>4</sub> does not.
Video consigliato:
Percorso guidato
05:04
Lewis Acids and Bases

Oxidation States and Stability

The oxidation state of an element in a compound can influence its reactivity and stability. In GeCl<sub>4</sub>, germanium is in the +4 oxidation state, which allows it to stabilize additional negative charges when reacting with Cl<sup>-</sup>. In contrast, CCl<sub>4</sub> does not have a favorable oxidation state for further reaction with Cl<sup>-</sup>, leading to its inertness in this scenario.
Video consigliato:
Percorso guidato
02:42
Oxidation Numbers
Pratica correlata
Domanda del libro di testo

Look at the location of elements A, B, C, and D in the following periodic table:

(d) Which hydrides react with water to give an acidic solution, and which give a basic solution?

102
views
Domanda del libro di testo

Which of the following oxides will be more soluble in acidic solution? (LO 22.14)

(a) SiO2 (b) NO2

(c) BaO (d) B2O3

97
views
Domanda del libro di testo

In what forms is oxygen commonly found in nature?

96
views
Domanda del libro di testo

Compare some of the physical properties of H2S, NaH, and PdHx.

84
views
Domanda del libro di testo

The following models represent the structures of binary hydrides

of second-row elements:

(a) Identify the nonhydrogen atom in each case, and write the molecular formula for each hydride.

106
views
Domanda del libro di testo

Look at the location of elements A, B, C, and D in the following

periodic table:

(c) Which hydrides react with water to give H2 gas? Write a balanced net ionic equation for each reaction.

100
views