Skip to main content
Ch.13 - Solutions
Tro - Chemistry: A Molecular Approach 4th Edition
Tro4th EditionChemistry: A Molecular ApproachISBN: 9780134112831Non è quello che usi tu?Cambia libro di testo
Capitolo 13, Problema 78

An ethylene glycol solution contains 21.2 g of ethylene glycol (C2H6O2) in 85.4 mL of water. Determine the freezing point and boiling point of the solution. (Assume a density of 1.00 g/mL for water.)

Guida verificata passo dopo passo
1
Calculate the molality of the solution by first determining the moles of ethylene glycol (C_2H_6O_2) using its molar mass.
Convert the volume of water to mass using the given density (1.00 g/mL), then use this mass to calculate the molality of the solution.
Use the freezing point depression formula, \( \Delta T_f = i \cdot K_f \cdot m \), where \( i \) is the van't Hoff factor (1 for ethylene glycol), \( K_f \) is the freezing point depression constant for water, and \( m \) is the molality.
Calculate the new freezing point by subtracting \( \Delta T_f \) from the normal freezing point of water (0°C).
Use the boiling point elevation formula, \( \Delta T_b = i \cdot K_b \cdot m \), where \( K_b \) is the boiling point elevation constant for water, to find the change in boiling point, and add \( \Delta T_b \) to the normal boiling point of water (100°C).

Concetti chiave

Ecco i concetti essenziali che devi comprendere per rispondere correttamente alla domanda.

Colligative Properties

Colligative properties are physical properties of solutions that depend on the number of solute particles in a given amount of solvent, rather than the identity of the solute. These properties include boiling point elevation and freezing point depression, which are crucial for determining how the presence of a solute like ethylene glycol affects the freezing and boiling points of water.
Video consigliato:
Percorso guidato
01:26
Colligative Properties

Freezing Point Depression

Freezing point depression is a colligative property that describes the lowering of the freezing point of a solvent when a solute is added. The extent of this depression can be calculated using the formula ΔTf = i * Kf * m, where ΔTf is the change in freezing point, Kf is the freezing point depression constant of the solvent, and m is the molality of the solution.
Video consigliato:
Percorso guidato
01:59
Freezing Point Depression

Boiling Point Elevation

Boiling point elevation is another colligative property that indicates the increase in the boiling point of a solvent when a solute is dissolved in it. This can be calculated using the formula ΔTb = i * Kb * m, where ΔTb is the change in boiling point, Kb is the boiling point elevation constant of the solvent, and m is the molality of the solution. Understanding this concept is essential for determining how the boiling point of water changes in the presence of ethylene glycol.
Video consigliato:
Percorso guidato
03:05
Boiling Point Elevation