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Ch.16 - Acids and Bases
Tro - Chemistry: A Molecular Approach 4th Edition
Tro4th EditionChemistry: A Molecular ApproachISBN: 9780134112831Non è quello che usi tu?Cambia libro di testo
Capitolo 16, Problema 131

People often take milk of magnesia to reduce the discomfort associated with acid stomach or heartburn. The recommended dose is 1 teaspoon, which contains 4.00×102 mg of Mg(OH)2. What volume of an HCl solution with a pH of 1.3 can be neutralized by one dose of milk of magnesia? If the stomach contains 2.00×102 mL of pH 1.3 solution, is all the acid neutralized? If not, what fraction is neutralized?

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1
Calculate the moles of Mg(OH)_2 in the recommended dose using its molar mass.
Write the balanced chemical equation for the neutralization reaction: Mg(OH)_2 + 2HCl -> MgCl_2 + 2H_2O.
Determine the moles of HCl that can be neutralized by the moles of Mg(OH)_2 using the stoichiometry from the balanced equation.
Calculate the concentration of HCl from the given pH using the formula: [H^+] = 10^{-pH}.
Determine the volume of HCl solution that can be neutralized by the moles of HCl calculated, and compare it to the given volume of stomach acid to find the fraction neutralized.

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Neutralization Reaction

A neutralization reaction occurs when an acid reacts with a base to produce water and a salt. In this case, magnesium hydroxide (Mg(OH)2) acts as a base that neutralizes hydrochloric acid (HCl). The balanced chemical equation for this reaction is Mg(OH)2 + 2HCl → MgCl2 + 2H2O, which illustrates how the acid and base interact to reduce acidity.
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pH and Concentration

pH is a measure of the hydrogen ion concentration in a solution, indicating its acidity or basicity. A pH of 1.3 corresponds to a high concentration of H+ ions, specifically 0.050 M HCl. Understanding pH is crucial for calculating how much acid can be neutralized by a given amount of base, as it directly relates to the concentration of the acid present in the solution.
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Stoichiometry

Stoichiometry involves the calculation of reactants and products in chemical reactions based on their molar ratios. In this scenario, stoichiometry is used to determine how many moles of HCl can be neutralized by the available moles of Mg(OH)2 from the milk of magnesia. This concept is essential for quantifying the extent of the neutralization and assessing whether all the acid in the stomach can be neutralized.
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Stoichiometry Concept