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Ch.20 - Radioactivity and Nuclear Chemistry
Tro - Chemistry: A Molecular Approach 4th Edition
Tro4th EditionChemistry: A Molecular ApproachISBN: 9780134112831Non è quello che usi tu?Cambia libro di testo
Capitolo 20, Problema 96

The half-life of 235U, an alpha emitter, is 7.1⨉108 years. Calculate the number of alpha particles emitted by 1.0 mg of this nuclide in 1.0 minute.

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1
Determine the number of moles of 235U in 1.0 mg. Use the molar mass of 235U, which is approximately 235 g/mol.
Calculate the number of atoms of 235U using Avogadro's number (6.022 × 10^23 atoms/mol).
Use the half-life formula to find the decay constant (k) for 235U: k = \(\frac{\ln(2)}{\text{half-life}\)}.
Calculate the number of decays (and thus alpha particles emitted) in 1.0 minute using the formula: N = N_0 (1 - e^{-kt}), where N_0 is the initial number of atoms and t is the time in minutes.
Convert the time from minutes to years if necessary, and solve for the number of alpha particles emitted.

Concetti chiave

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Half-life

Half-life is the time required for half of the radioactive nuclei in a sample to decay. For uranium-235, which has a half-life of 7.1 × 10^8 years, this means that after this period, only half of the original amount of uranium-235 will remain, while the other half has transformed into other elements through radioactive decay.
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Zero-Order Half-life

Radioactive Decay

Radioactive decay is the process by which unstable atomic nuclei lose energy by emitting radiation, such as alpha particles. In the case of uranium-235, it decays by emitting alpha particles, which consist of two protons and two neutrons, effectively reducing the atomic number and mass of the original nucleus.
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Rate of Radioactive Decay

Activity and Emission Rate

The activity of a radioactive sample is defined as the number of decays per unit time, typically measured in becquerels (Bq). To calculate the number of alpha particles emitted by a sample, one can use the activity formula, which incorporates the number of radioactive atoms present and the decay constant derived from the half-life, allowing for the determination of emissions over a specified time frame.
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Emission Spectra