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Ch.6 - Thermochemistry
Tro - Chemistry: A Molecular Approach 4th Edition
Tro4th EditionChemistry: A Molecular ApproachISBN: 9780134112831Non è quello che usi tu?Cambia libro di testo
Capitolo 6, Problema 77a

For each generic reaction, determine the value of ΔH2 in terms of ΔH1.
a. A + B → 2 C ΔH1
2 C→ A + B ΔH2 = ?

Guida verificata passo dopo passo
1
insert step 1> Identify the type of reaction given in the problem. The first reaction is A + B \(\rightarrow\) 2C with an enthalpy change of \(\Delta\) H_1.
insert step 2> Recognize that the second reaction is the reverse of the first reaction: 2C \(\rightarrow\) A + B.
insert step 3> Understand that reversing a chemical reaction changes the sign of the enthalpy change. Therefore, \(\Delta\) H_2 will be the negative of \(\Delta\) H_1.
insert step 4> Express \(\Delta\) H_2 in terms of \(\Delta\) H_1: \(\Delta\) H_2 = -\(\Delta\) H_1.
insert step 5> Conclude that the enthalpy change for the reverse reaction is the negative of the enthalpy change for the forward reaction.

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Concetti chiave

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Enthalpy Change (ΔH)

Enthalpy change (ΔH) is a measure of the heat content of a system at constant pressure. It indicates whether a reaction is exothermic (releases heat, ΔH < 0) or endothermic (absorbs heat, ΔH > 0). Understanding ΔH is crucial for predicting the energy changes associated with chemical reactions.
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Enthalpy of Formation

Hess's Law

Hess's Law states that the total enthalpy change for a reaction is the same, regardless of the number of steps taken to achieve the reaction. This principle allows us to calculate the enthalpy change of a reaction by using the enthalpy changes of related reactions, making it essential for determining ΔH2 in terms of ΔH1.
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Reversible Reactions

Reversible reactions can proceed in both forward and reverse directions, allowing for the establishment of equilibrium. The relationship between the forward and reverse reactions is critical in determining the enthalpy changes, as the enthalpy change for the reverse reaction is equal in magnitude but opposite in sign to that of the forward reaction.
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Reversible Changes in Matter
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For each generic reaction, determine the value of ΔH2 in terms of ΔH1.

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Consider the generic reaction:

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For each generic reaction, determine the value of ΔH2 in terms of ΔH1.

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