Domanda del libro di testo
Ethanol is a possible fuel. Use average bond energies to calculate ΔHrxn for the combustion of ethanol. CH3CH2OH(g) + 3 O2(g) → 2 CO2(g) + 3 H2O(g)
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Ch.10 - Chemical Bonding I: The Lewis Model
Tro6th EditionChemistry: A Molecular ApproachISBN: 9780137832217
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TOC.tableOfContents
- Ch.1 - Matter, Measurement & Problem Solving118
- Ch.2 - Atoms & Elements106
- Ch.3 - Molecules and Compounds131
- Ch.4 - Chemical Reactions and Chemical Quantities56
- Ch.5 - Introduction to Solutions and Aqueous Solutions82
- Ch.6 - Gases114
- Ch.7 - Thermochemistry96
- Ch.8 - The Quantum-Mechanical Model of the Atom60
- Ch.9 - Periodic Properties of the Elements90
- Ch.10 - Chemical Bonding I: The Lewis Model89
- Ch.11 - Chemical Bonding II: Molecular Shapes, VSEPR & MO Theory85
- Ch.12 - Liquids, Solids & Intermolecular Forces51
- Ch.13 - Solids & Modern Materials47
- Ch.14 - Solutions90
- Ch.15 - Chemical Kinetics115
- Ch.16 - Chemical Equilibrium68
- Ch.17 - Acids and Bases136
- Ch.18 - Aqueous Ionic Equilibrium153
- Ch.19 - Free Energy & Thermodynamics93
- Ch.20 - Electrochemistry106
- Ch.21 - Radioactivity & Nuclear Chemistry74
- Ch.22 - Organic Chemistry140
Tro6th EditionChemistry: A Molecular ApproachISBN: 9780137832217Non è quello che usi tu?Cambia libro di testo
Capitolo 10, Problema 90
In the Chemistry and the Environment box on free radicals in this chapter, we discussed the importance of the hydroxyl radical in reacting with and eliminating many atmospheric pollutants. However, the hydroxyl radical does not clean up everything. For example, chlorofluorocarbons—which destroy stratospheric ozone—are not attacked by the hydroxyl radical. Consider the hypothetical reaction by which the hydroxyl radical might react with a chlorofluorocarbon: OH(g) + CF2Cl2(g) → HOF(g) + CFCl2(g) Use bond energies to explain why this reaction is improbable. (The C–F bond energy is 552 kJ/mol.)
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Identify the bonds broken and formed in the reaction: OH(g) + CF_2Cl_2(g) -> HOF(g) + CFCl_2(g).
Calculate the total energy required to break the bonds in the reactants. This includes the O-H bond in OH and one C-F bond in CF_2Cl_2.
Calculate the total energy released when new bonds are formed in the products. This includes the H-O bond in HOF and the C-Cl bond in CFCl_2.
Use the bond energies to calculate the net energy change for the reaction: Net energy change = (Energy required to break bonds) - (Energy released in forming bonds).
Discuss the significance of the net energy change: If the net energy change is positive, the reaction is endothermic and less likely to occur spontaneously, explaining why the reaction is improbable.
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Bond Energy
Bond energy is the amount of energy required to break a bond between two atoms in a molecule. It is a crucial factor in determining the feasibility of a chemical reaction. In the context of the reaction between the hydroxyl radical and chlorofluorocarbon, the high bond energy of the C-F bond (552 kJ/mol) suggests that breaking this bond requires significant energy, making the reaction less likely to occur spontaneously.
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Percorso guidato
01:50
Bond Energy
Reaction Mechanism
A reaction mechanism describes the step-by-step sequence of elementary reactions by which overall chemical change occurs. Understanding the mechanism helps predict whether a reaction will proceed based on the stability of intermediates and the energy required to break existing bonds. In this case, the mechanism would involve the formation of new bonds and the breaking of strong C-F bonds, which complicates the likelihood of the reaction occurring.
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Percorso guidato
03:06Reaction Mechanism Overview
Thermodynamics of Reactions
Thermodynamics in chemistry refers to the study of energy changes during chemical reactions. The Gibbs free energy change (ΔG) determines whether a reaction is spontaneous. If the energy required to break the C-F bond exceeds the energy released from forming new bonds, the reaction will not be favorable. Thus, analyzing the thermodynamic aspects of the proposed reaction is essential to understand its improbability.
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Percorso guidato
01:18First Law of Thermodynamics
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Domanda del libro di testo
Write an appropriate Lewis structure for each compound. Make certain to distinguish between ionic and molecular compounds. b. ClF5
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Domanda del libro di testo
Ethane burns in air to form carbon dixode and water vapor.
2 H3C¬CH3( g) + 7 O2( g)¡4 CO2( g) + 6 H2O( g)
Use average bond energies to calculate ΔHrxn for the reaction.
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Domanda del libro di testo
Hydrogenation reactions are used to add hydrogen across double bonds in hydrocarbons and other organic compounds. Use average bond energies to calculate ΔHrxn for the hydrogenation reaction. H2C=CH2(g) + H2(g) → H3C–CH3(g)
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Domanda del libro di testo
Each compound contains both ionic and covalent bonds. Write ionic Lewis structures for each, including the covalent structure for the ion in brackets. Write resonance structures if necessary. a. BaCO3
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