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Introduction to Chemistry - Key Concepts

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  • Law of Conservation of Mass

    Matter is neither created nor destroyed in a chemical reaction; total mass of reactants equals total mass of products.

  • Law of Definite Proportions

    Different samples of a pure compound always contain the same proportion of elements by mass.

  • Law of Multiple Proportions

    Elements combine in different ways to form different compounds, with mass ratios that are small whole-number multiples of each other.

  • Dalton's Atomic Theory - Key Points

    Atoms are tiny, indestructible particles; atoms of the same element have the same mass; atoms combine in whole-number ratios; chemical reactions rearrange atoms.

  • Discovery of the Electron

    J.J. Thomson discovered the electron as a tiny, negatively charged particle using cathode-ray tube experiments.

  • Millikan Oil-Drop Experiment

    Determined the charge and mass of the electron by observing charged oil drops in an electric field.

  • Plum Pudding Model

    Model where electrons are embedded in a uniform positive charge 'soup' within the atom.

  • Radioactivity and Particles

    Radiation consists of alpha particles (helium nuclei) and beta particles (high-energy electrons).

  • Rutherford's Gold-Foil Experiment

    Showed that atoms are mostly empty space with a small, dense, positively charged nucleus.

  • Atomic Number (Z)

    The number of protons in the nucleus; equals the number of electrons in a neutral atom.

  • Mass Number (A)

    The sum of the number of protons and neutrons in the nucleus.

  • Isotopes

    Atoms with the same atomic number but different mass numbers due to varying neutrons.

  • Ions

    Atoms that have gained or lost electrons, becoming charged particles: cations (+) and anions (−).

  • Atomic Mass Unit (amu)

    Defined as 1/12 the mass of a carbon-12 atom; also called Dalton (Da).

  • Atomic Mass

    The weighted average of the isotopic masses of an element's naturally occurring isotopes.

  • Natural Abundance

    The percentage of each isotope present in a naturally occurring sample of an element.

  • The Mole (mol)

    SI unit for amount of substance; 1 mol = 6.022 × 10\(23\) particles.

  • Molar Mass

    The mass in grams of 1 mole of an element; numerically equal to the atomic mass in amu.

  • Conversion between mass and moles

    Use molar mass as a conversion factor: \(\text{mass (g)} \leftrightarrow \text{moles}\).

  • Conversion between moles and number of particles

    Use Avogadro's number as a conversion factor: \(\text{moles} \leftrightarrow \text{number of particles}\).