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Ch. 24 - Benzene 2: Reactions Influenced by the Aromatic Ring
Mullins - Organic Chemistry: A Learner Centered Approach 1st Edition
Mullins1st EditionOrganic Chemistry: A Learner Centered ApproachISBN: 9780137566471Non è quello che usi tu?Cambia libro di testo
Capitolo 23, Problema 33a

Predict the product of the following reactions.
(a) Chemical structure showing ether cleavage reaction with hydrogen and palladium catalyst.

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Identify the functional groups present in the starting material. The molecule contains an ester linkage and a ketone group.
Recognize the reagents used in the reaction: H2 and Pd^0. This combination is typically used for hydrogenation reactions, which can reduce double bonds and certain functional groups.
Consider the susceptibility of the functional groups to hydrogenation. The ketone group is likely to be reduced to an alcohol under these conditions.
Predict the transformation of the ketone group. The carbonyl group (C=O) in the ketone will be reduced to a hydroxyl group (C-OH), resulting in a secondary alcohol.
Note that the ester linkage is generally stable under these conditions and is unlikely to be reduced. Therefore, the ester group remains unchanged in the product.

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