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Ch 19: Work, Heat, and the First Law of Thermodynamics
Knight Calc - Physics for Scientists and Engineers 5th Edition
Knight Calc5th EditionPhysics for Scientists and EngineersISBN: 9780137344796Non è quello che usi tu?Cambia libro di testo
Capitolo 19, Problema 56a

n moles of an ideal gas at temperature T1 and volume V1 expand isothermally until the volume has doubled. In terms of n, T1, and V1, what is the final temperature?

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Step 1: Recognize that the process described is isothermal, meaning the temperature of the gas remains constant throughout the expansion. Therefore, the final temperature T₂ is equal to the initial temperature T₁.
Step 2: Recall the ideal gas law, which is given by the equation: PV=nRT, where P is pressure, V is volume, n is the number of moles, R is the ideal gas constant, and T is temperature.
Step 3: Since the temperature remains constant (T₁ = T₂), the product of pressure and volume (P × V) must also remain constant during the isothermal process. This is expressed as: P1V1 = P2V2.
Step 4: In this problem, the volume doubles, so V2 = 2V1. Substituting this into the equation for isothermal processes, we find that the pressure must adjust accordingly to maintain the equality.
Step 5: Conclude that the final temperature T₂ is the same as the initial temperature T₁, as the isothermal condition ensures no change in temperature. Thus, T₂ = T₁.

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Ideal Gas Law

The Ideal Gas Law is a fundamental equation in thermodynamics that relates the pressure, volume, temperature, and number of moles of an ideal gas. It is expressed as PV = nRT, where P is pressure, V is volume, n is the number of moles, R is the ideal gas constant, and T is temperature. This law is crucial for understanding the behavior of gases under various conditions.
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Ideal Gases and the Ideal Gas Law

Isothermal Process

An isothermal process is a thermodynamic process that occurs at a constant temperature. For an ideal gas, this means that any expansion or compression of the gas occurs without a change in temperature, which implies that heat is exchanged with the surroundings to maintain thermal equilibrium. This concept is essential for analyzing the behavior of gases during expansion or compression.
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Entropy & Ideal Gas Processes

Doubling Volume in Isothermal Expansion

When an ideal gas undergoes isothermal expansion and its volume doubles, the pressure of the gas decreases according to Boyle's Law, which states that pressure is inversely proportional to volume at constant temperature. In this scenario, since the temperature remains constant, the final state of the gas can be analyzed using the Ideal Gas Law to determine how the pressure and other properties change as the volume increases.
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Volume Thermal Expansion