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Ch 20: The Micro/Macro Connection
Knight Calc - Physics for Scientists and Engineers 5th Edition
Knight Calc5th EditionPhysics for Scientists and EngineersISBN: 9780137344796Non è quello che usi tu?Cambia libro di testo
Capitolo 20, Problema 29

The thermal energy of 1.0 mol of a substance is increased by 1.0 J. What is the temperature change if the system is (a) a monatomic gas, (b) a diatomic gas, and (c) a solid?

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Step 1: Understand the relationship between thermal energy, temperature change, and heat capacity. The formula to use is ΔQ = n * C * ΔT, where ΔQ is the thermal energy added, n is the number of moles, C is the molar heat capacity, and ΔT is the temperature change.
Step 2: For a monatomic gas, the molar heat capacity at constant volume (C_v) is given by C_v = (3/2) * R, where R is the universal gas constant (R ≈ 8.314 J/(mol·K)). Substitute C_v into the formula ΔQ = n * C_v * ΔT and solve for ΔT.
Step 3: For a diatomic gas, the molar heat capacity at constant volume (C_v) is given by C_v = (5/2) * R. Substitute this value into the formula ΔQ = n * C_v * ΔT and solve for ΔT.
Step 4: For a solid, the molar heat capacity is typically approximated using the Dulong-Petit law, which states C ≈ 3 * R. Substitute this value into the formula ΔQ = n * C * ΔT and solve for ΔT.
Step 5: For each case (monatomic gas, diatomic gas, and solid), substitute the given values: ΔQ = 1.0 J and n = 1.0 mol into the respective formulas derived in steps 2, 3, and 4 to calculate the temperature change ΔT for each system.

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Specific Heat Capacity

Specific heat capacity is the amount of heat required to change the temperature of a unit mass of a substance by one degree Celsius. It varies for different materials and phases (solid, liquid, gas) and is crucial for calculating temperature changes when thermal energy is added or removed.
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Degrees of Freedom

Degrees of freedom refer to the number of independent ways in which a system can store energy. For gases, monatomic gases have three translational degrees of freedom, while diatomic gases have five (three translational and two rotational). This affects how they respond to added thermal energy.
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Heat Transfer in Phases

Heat transfer in phases describes how different states of matter (solid, liquid, gas) absorb and transfer heat. Solids typically have lower heat capacities compared to gases, and the way energy is distributed among particles varies significantly, influencing the temperature change for a given amount of thermal energy.
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