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Ch 41: Quantum Mechanics II: Atomic Structure
Young & Freedman Calc - University Physics 14th Edition
Young & Freedman Calc14th EditionUniversity PhysicsISBN: 9780321973610Non è quello che usi tu?Cambia libro di testo
Capitolo 41, Problema 34a

The energy of the 2s2s state of lithium is −5.391-5.391 eV. Calculate the value of ZeffZ_{eff} for this state.

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Understand the concept of effective nuclear charge (Zeff): Zeff is the net positive charge experienced by an electron in a multi-electron atom. It accounts for the shielding effect caused by other electrons.
Use the formula for the energy of an electron in a hydrogen-like atom: \( E_n = -13.6 \frac{Z_{\text{eff}}^2}{n^2} \) (in eV), where \( E_n \) is the energy of the electron, \( Z_{\text{eff}} \) is the effective nuclear charge, and \( n \) is the principal quantum number.
Rearrange the formula to solve for \( Z_{\text{eff}} \): \( Z_{\text{eff}} = \sqrt{\frac{-E_n \cdot n^2}{13.6}} \).
Substitute the given values into the formula: \( E_n = -5.391 \ \text{eV} \) and \( n = 2 \) (since the electron is in the 2s state).
Simplify the expression to calculate \( Z_{\text{eff}} \): Perform the square root and division operations to find the effective nuclear charge for the 2s state of lithium.

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Effective Nuclear Charge (Zeff)

Effective Nuclear Charge (Zeff) is the net positive charge experienced by an electron in a multi-electron atom. It accounts for the shielding effect caused by other electrons, which reduces the full nuclear charge. Zeff can be calculated using the formula Zeff = Z - S, where Z is the atomic number and S is the shielding constant. Understanding Zeff is crucial for predicting electron behavior and energy levels in atoms.
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Energy levels in atoms refer to the quantized states that electrons can occupy. Each energy level corresponds to a specific energy value, which is influenced by the nuclear charge and electron-electron interactions. The energy of an electron in a given state can be calculated using the formula E = -Zeff^2 * 13.6 eV/n^2, where n is the principal quantum number. This concept is essential for understanding electron configurations and transitions.
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