General Biology: Chemistry and Water Basics
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Matter is anything with mass that takes up space.
Element is a pure substance made of one type of atom. Atom is the smallest unit of an element and matter.
Proton: +1 charge, ~1 amu, in nucleus.
Neutron: 0 charge, ~1 amu, in nucleus.
Electron: -1 charge, ~0 amu, in shells around nucleus.
CHNOPS: Carbon, Hydrogen, Nitrogen, Oxygen, Phosphorus, Sulfur make up ~97% of mass in organisms.
Atomic number: number of protons.
Mass number: protons + neutrons.
Atomic mass: average mass of all isotopes.
Valence electrons are electrons in the outermost shell; they determine chemical bonding and reactivity.
Atoms are most stable when their valence shell is full, usually 8 electrons in the second shell.
Isotopes have same protons but different neutrons.
Radioactive isotopes decay, releasing energy and particles.
Chemical bond: force holding atoms together.
Molecule: ≥2 bonded atoms.
Compound: molecule with ≥2 different elements.
Intramolecular: bonds within a molecule.
Intermolecular: interactions between molecules.
Covalent bond: sharing electrons.
Electronegativity difference causes nonpolar (equal sharing) or polar (unequal sharing) bonds.
Nonpolar: H–H, O–O, C–H.
Polar: H–Cl, O–H in water, N–H in ammonia.
Ionic bonds: attraction between oppositely charged ions.
Hydrogen bonds: weak attraction between H and F, O, or N atoms.
Water has polar covalent O–H bonds; oxygen is partially negative (9delta^-9), hydrogens partially positive (9delta^+9), enabling hydrogen bonding between molecules.
Cohesion/adhesion/surface tension, ice less dense than liquid, high specific heat and heat of vaporization, universal solvent.
Cohesion: water sticks to water.
Adhesion: water sticks to other polar surfaces.
Together create surface tension.
Ice forms a stable hydrogen-bond lattice that spreads molecules apart, lowering density so ice floats.
Specific heat is heat needed to raise 1 g by 19C. Water's high value helps resist temperature changes, aiding homeostasis.
Solvent: dissolves substances.
Solute: dissolved substance.
Solution: solute + solvent mixture.
Hydrophilic: water-loving, usually polar or charged, dissolves well.
Hydrophobic: water-fearing, nonpolar, does not dissolve.
pH is a logarithmic scale measuring hydrogen ion concentration: acidic (<7, high [H^+]), neutral (=7), basic (>7, low [H^+]).
Buffers accept or donate H^+ ions to resist pH changes, keeping biological systems near neutral pH.