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General Chemistry
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Coordination Isomers definitions
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Isomers
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Isomers
Compounds with the same molecular formula but different structures due to varied atom connections.
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Isomers
Compounds with the same molecular formula but different structures due to varied atom connections.
Constitutional Isomers
Isomers with different connections among atoms, also known as structural isomers.
Coordination Isomers
Isomers where the composition of the complex ion changes, involving ligand or counter ion swapping.
Linkage Isomers
Isomers differing in the donor atom of a ligand, such as thiocyanate linking through sulfur or nitrogen.
Stereo Isomers
Isomers with the same connections but different spatial arrangements, including chiral centers.
Chiral Center
An atom connected to four different groups, leading to optical isomerism.
Enantiomers
Mirror image isomers that are non-superimposable, often involving chiral centers.
Geometric Isomers
Isomers differing in spatial arrangement, such as cis and trans configurations.
Cis Configuration
Arrangement where similar ligands are on the same side of a central atom.
Trans Configuration
Arrangement where similar ligands are on opposite sides of a central atom.
Octahedral
A molecular geometry with six ligands symmetrically arranged around a central atom.
Ligand
An ion or molecule that binds to a central metal atom to form a coordination complex.
Counter Ion
An ion that balances the charge of a complex ion in a coordination compound.
Thiocyanate
A monodentate ligand that can bind through sulfur or nitrogen atoms.
Diastereomers
Isomers that are not mirror images and differ in spatial arrangement, such as cis-trans isomers.