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Galvanic Cell quiz
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What is the main function of a galvanic (voltaic) cell?
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What is the main function of a galvanic (voltaic) cell?
A galvanic cell converts stored chemical energy into electrical energy through spontaneous redox reactions.
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What is the main function of a galvanic (voltaic) cell?
A galvanic cell converts stored chemical energy into electrical energy through spontaneous redox reactions.
Where does oxidation occur in a galvanic cell?
Oxidation occurs at the anode, where electrons are lost.
Where does reduction occur in a galvanic cell?
Reduction occurs at the cathode, where electrons are gained.
What is the charge of the anode and cathode in a galvanic cell?
The anode is negatively charged, and the cathode is positively charged.
What happens to the mass of the anode and cathode over time in a galvanic cell?
The anode loses mass as it dissolves, while the cathode gains mass as cations plate onto it.
What is the purpose of the salt bridge in a galvanic cell?
The salt bridge allows the flow of neutral spectator ions to maintain charge balance and complete the circuit.
How do electrons flow in a galvanic cell?
Electrons flow from the anode to the cathode through the external circuit.
What does a positive standard cell potential (E°cell) indicate about a galvanic cell?
A positive E°cell indicates the reaction is spontaneous.
What are the standard conditions for measuring cell potential?
Standard conditions are 1 M concentration, 1 atm pressure, and pH 7.
What happens to a galvanic cell when it reaches equilibrium?
When at equilibrium, the cell's ΔG°, E°cell, and ΔS° are zero, K equals one, and the cell is a 'dead battery.'
How does the salt bridge help maintain electron flow in a galvanic cell?
It prevents charge buildup by allowing negative ions to flow toward the anode and positive ions toward the cathode.
What is the relationship between cell potential and the likelihood of reduction?
The greater the cell potential, the more likely reduction will occur at that electrode.
What periodic trends are important for galvanic cell operation?
Low ionization energy at the anode and high electron affinity at the cathode favor electron flow.
What are the signs of ΔG°, ΔS°, and K for a spontaneous galvanic cell reaction?
ΔG° is negative, ΔS° is positive, and K is greater than one.
What does 'plating out' mean at the cathode in a galvanic cell?
'Plating out' refers to cations in solution gaining electrons and forming a solid layer on the cathode, increasing its mass.