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Ch.11 - Liquids, Solids & Intermolecular Forces
Tro - Chemistry: A Molecular Approach 4th Edition
Tro4th EditionChemistry: A Molecular ApproachISBN: 9780134112831당신이 사용하는 게 아니라요?교과서 변경
11장, 문제 86

The vapor pressure of CCl3F at 300 K is 856 torr. If 11.5 g of CCl3F is enclosed in a 1.0-L container, will any liquid be present? If so, what mass of liquid?

검증된 단계별 안내
1
Calculate the number of moles of CCl_3F using its molar mass.
Use the ideal gas law, PV = nRT, to calculate the pressure exerted by the gas if all the CCl_3F were in the gaseous state.
Compare the calculated pressure with the given vapor pressure of CCl_3F at 300 K.
If the calculated pressure is greater than the vapor pressure, some liquid will be present. Calculate the moles of gas that would exert the vapor pressure using the ideal gas law.
Subtract the moles of gas from the total moles to find the moles of liquid, then convert this to mass using the molar mass.

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이 영상 해법은 위 문제에 도움이 된다고 튜터들이 추천한 것입니다.
영상 길이:
4m

주요 개념

질문에 올바르게 답하기 위해 반드시 이해해야 하는 핵심 개념들은 다음과 같습니다.

Vapor Pressure

Vapor pressure is the pressure exerted by a vapor in equilibrium with its liquid or solid phase at a given temperature. It indicates the tendency of a substance to evaporate; higher vapor pressure means a greater tendency to vaporize. In this context, the vapor pressure of CCl3F at 300 K is 856 torr, which serves as a critical threshold for determining whether liquid will remain in the container.
추천 영상:
가이드 코스
02:40
Raoult's Law and Vapor Pressure

Ideal Gas Law

The Ideal Gas Law relates the pressure, volume, temperature, and number of moles of a gas through the equation PV = nRT. This law helps in calculating the number of moles of CCl3F present in the container, which is essential for comparing it to the vapor pressure. Understanding this relationship allows us to determine if the conditions favor the presence of liquid or if all the substance will be in the gaseous state.
추천 영상:
가이드 코스
01:15
Ideal Gas Law Formula

Phase Equilibrium

Phase equilibrium occurs when the rates of evaporation and condensation of a substance are equal, resulting in a stable mixture of liquid and vapor. In this scenario, if the number of moles of CCl3F exceeds what can exist as vapor at the given vapor pressure, some of it will remain as liquid. Analyzing the mass of CCl3F and its vapor pressure helps in assessing whether liquid will be present in the container.
추천 영상:
가이드 코스
03:22
Phase Changes in Diagrams