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Ch.19 - Free Energy & Thermodynamics
Tro - Chemistry: A Molecular Approach 6th Edition
Tro6th EditionChemistry: A Molecular ApproachISBN: 9780137832217당신이 사용하는 게 아니라요?교과서 변경
19장, 문제 46

Calculate the change in Gibbs free energy for each of the sets of ΔH°rxn, ΔS°rxn, and T given in Problem 44. Predict whether or not each reaction is spontaneous at the temperature indicated. (Assume that all reactants and products are in their standard states.)

검증된 단계별 안내
1
Identify the formula for Gibbs free energy change: \( \Delta G^\circ = \Delta H^\circ - T \Delta S^\circ \).
Substitute the given values for \( \Delta H^\circ_{rxn} \), \( \Delta S^\circ_{rxn} \), and \( T \) into the formula.
Ensure that the units are consistent, typically converting \( \Delta S^\circ_{rxn} \) from J/mol·K to kJ/mol·K by dividing by 1000, if necessary.
Calculate \( \Delta G^\circ \) using the substituted values.
Determine spontaneity: if \( \Delta G^\circ < 0 \), the reaction is spontaneous; if \( \Delta G^\circ > 0 \), it is non-spontaneous.

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이 영상 해법은 위 문제에 도움이 된다고 튜터들이 추천한 것입니다.
영상 길이:
4m

주요 개념

질문에 올바르게 답하기 위해 반드시 이해해야 하는 핵심 개념들은 다음과 같습니다.

Gibbs Free Energy (G)

Gibbs free energy is a thermodynamic potential that measures the maximum reversible work obtainable from a thermodynamic system at constant temperature and pressure. It is defined by the equation G = H - TS, where H is enthalpy, T is temperature, and S is entropy. A negative change in Gibbs free energy (ΔG < 0) indicates that a reaction is spontaneous, while a positive change (ΔG > 0) suggests non-spontaneity.
추천 영상:
가이드 코스
01:51
Gibbs Free Energy of Reactions

Enthalpy (ΔH°<sub>rxn</sub>)

Enthalpy change (ΔH°<sub>rxn</sub>) is the heat content change associated with a chemical reaction at standard conditions. It can be either exothermic (releasing heat, ΔH < 0) or endothermic (absorbing heat, ΔH > 0). The sign and magnitude of ΔH°<sub>rxn</sub> significantly influence the spontaneity of a reaction, as it contributes to the overall Gibbs free energy change.
추천 영상:
가이드 코스
03:17
Enthalpy of Formation Example 1

Entropy (ΔS°<sub>rxn</sub>)

Entropy (ΔS°<sub>rxn</sub>) is a measure of the disorder or randomness in a system. In the context of a chemical reaction, an increase in entropy (ΔS > 0) generally favors spontaneity, as systems tend to evolve towards greater disorder. The relationship between entropy, enthalpy, and temperature is crucial for determining the spontaneity of reactions through the Gibbs free energy equation.
추천 영상:
가이드 코스
02:07
Entropy and Physical Changes Example