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Ch. 15 - Reactions of Carboxylic Acids and Carboxylic Acid Derivatives
Bruice - Organic Chemistry 8th Edition
Bruice8th EditionOrganic ChemistryISBN: 9780135213711당신이 사용하는 게 아니라요?교과서 변경
15장, 문제 48g

Draw a structure for each of the following:
g. benzoic anhydride

검증된 단계별 안내
1
Step 1: Understand the structure of benzoic acid. Benzoic acid is an aromatic carboxylic acid with the formula C₆H₅COOH. It consists of a benzene ring (C₆H₅) attached to a carboxylic acid group (-COOH).
Step 2: Recall the structure of an anhydride. An anhydride is formed by the condensation of two carboxylic acid molecules, where a water molecule is removed. The general structure of an anhydride is R-CO-O-CO-R, where R represents the organic groups.
Step 3: Combine two benzoic acid molecules to form benzoic anhydride. Remove one molecule of water (H₂O) by eliminating an -OH group from one benzoic acid molecule and an -H from the other. This results in the formation of a bond between the two carbonyl groups through an oxygen atom.
Step 4: Draw the structure of benzoic anhydride. The structure will have two benzene rings (C₆H₅) attached to a central anhydride group (-CO-O-CO-). Each benzene ring is connected to a carbonyl group (C=O).
Step 5: Verify the structure. Ensure that the central oxygen atom is bonded to two carbonyl groups, and each carbonyl group is attached to a benzene ring. This confirms the correct structure of benzoic anhydride.

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이 영상 해법은 위 문제에 도움이 된다고 튜터들이 추천한 것입니다.
영상 길이:
3m

주요 개념

질문에 올바르게 답하기 위해 반드시 이해해야 하는 핵심 개념들은 다음과 같습니다.

Anhydrides

Anhydrides are compounds formed from the removal of water from two carboxylic acids. They can be classified as either symmetric or asymmetric, depending on whether the two acids are the same or different. In organic chemistry, anhydrides are important for various reactions, including acylation, where they can react with nucleophiles to form esters or amides.
추천 영상:
03:35
Anhydride Nomenclature

Benzoic Acid

Benzoic acid is a simple aromatic carboxylic acid with the formula C6H5COOH. It consists of a benzene ring attached to a carboxyl group (-COOH). Understanding benzoic acid is crucial for drawing benzoic anhydride, as the anhydride is derived from two benzoic acid molecules through the loss of water.
추천 영상:
00:49
Which alkylbenzene would NOT yield benzoic acid, treated with KMnO4

Structural Representation

Structural representation in organic chemistry involves depicting the arrangement of atoms within a molecule, including bonds and functional groups. For benzoic anhydride, it is essential to illustrate the two benzoic acid units connected by an anhydride bond (–C(=O)–O–C(=O)–). Mastery of structural representation aids in visualizing molecular interactions and predicting reactivity.
추천 영상:
05:09
Representations of L-Configuration