Ch. 16 - Reactions of Aldehydes and Ketones • More Reactions of Carboxylic Acid Derivatives

Bruice8th EditionOrganic ChemistryISBN: 9780135213711당신이 사용하는 게 아니라요?교과서 변경

Bruice 8th Edition

Ch. 16 - Reactions of Aldehydes and Ketones • More Reactions of Carboxylic Acid Derivatives

문제 54h

16장, 문제 54h

What are the products of the following reactions?
h.

검증된 단계별 안내

Step 1: Identify the functional group in the reactant. The reactant contains a nitrile group (-C≡N), which is a carbon triple-bonded to a nitrogen atom.

Step 2: Recognize the reaction conditions. The presence of hydrogen gas (H₂) and Raney nickel indicates a catalytic hydrogenation reaction.

Step 3: Understand the mechanism of catalytic hydrogenation. Under these conditions, the nitrile group undergoes reduction, where the triple bond is broken, and hydrogen atoms are added to form an amine group (-CH₂-NH₂).

Step 4: Analyze the structure of the product. The cyclohexane ring remains intact, and the nitrile group is converted into a primary amine (-CH₂-NH₂).

Step 5: Write the final product structure. The product is cyclohexylamine, which has the formula C₆H₁₁-NH₂.

비슷한 문제에 대한 검증된 영상 답변:

이 영상 해법은 위 문제에 도움이 된다고 튜터들이 추천한 것입니다.

영상 길이:

주요 개념

질문에 올바르게 답하기 위해 반드시 이해해야 하는 핵심 개념들은 다음과 같습니다.

Alkynes

Alkynes are hydrocarbons that contain at least one carbon-carbon triple bond. They are unsaturated compounds and are generally more reactive than alkenes and alkanes due to the presence of the triple bond. In organic reactions, alkynes can undergo various transformations, including hydrogenation, where they react with hydrogen to form alkenes or alkanes.

Hydrogenation

Hydrogenation is a chemical reaction that involves the addition of hydrogen (H2) to a compound, typically in the presence of a catalyst. This process is commonly used to convert unsaturated hydrocarbons, such as alkynes and alkenes, into saturated hydrocarbons. The catalyst, such as Raney nickel, facilitates the reaction by lowering the activation energy required for the hydrogen to add across the multiple bonds.

Raney Nickel Catalyst

Raney nickel is a finely divided nickel-aluminum alloy that serves as a catalyst in hydrogenation reactions. It is particularly effective for reducing alkynes and alkenes to alkanes. The high surface area of Raney nickel enhances its catalytic activity, allowing for efficient hydrogenation under mild conditions, making it a valuable tool in organic synthesis.

What are the products of the following reactions?h.