When 2-bromopropane is treated with sodium ethoxide, propene is produced. What molecule is lost from 2-bromopropane in this process?

검증된 단계별 안내

Step 1: Recognize the type of reaction occurring. This is an elimination reaction (E2 mechanism), where a molecule is lost from the substrate to form a double bond.

Step 2: Identify the substrate, 2-bromopropane, and note that it contains a bromine atom attached to the second carbon of a propane chain.

Step 3: Understand the role of sodium ethoxide (NaOCH₂CH₃). It acts as a strong base, abstracting a proton (H⁺) from a β-carbon (the carbon adjacent to the carbon bonded to bromine).

Step 4: Determine the molecule lost during the reaction. The bromine atom leaves as a bromide ion (Br⁻), and a proton (H⁺) is abstracted from the β-carbon, resulting in the formation of propene (CH₃-CH=CH₂). The lost molecule is HBr (hydrogen bromide).

Step 5: Summarize the process: Sodium ethoxide facilitates the elimination of HBr from 2-bromopropane, leading to the formation of propene via the E2 mechanism.

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주요 개념

질문에 올바르게 답하기 위해 반드시 이해해야 하는 핵심 개념들은 다음과 같습니다.

Elimination Reactions

Elimination reactions involve the removal of a small molecule from a larger one, resulting in the formation of a double bond. In the case of 2-bromopropane reacting with sodium ethoxide, an elimination reaction occurs, leading to the formation of propene. Understanding the mechanism of elimination is crucial for predicting the products of such reactions.

Leaving Groups

A leaving group is an atom or group that can depart from the parent molecule during a chemical reaction. In the context of 2-bromopropane, the bromine atom acts as a leaving group when the sodium ethoxide facilitates the elimination process. The stability and ability of the leaving group to depart significantly influence the reaction's efficiency.

Base-Induced Elimination

Base-induced elimination refers to the process where a strong base, such as sodium ethoxide, abstracts a proton from a β-carbon, leading to the formation of a double bond. This mechanism is essential in understanding how propene is generated from 2-bromopropane, as the base facilitates the removal of a hydrogen atom alongside the leaving group.