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Ch. 4 - Acids and Bases/Electron Flow
Mullins - Organic Chemistry: A Learner Centered Approach 1st Edition
Mullins1st EditionOrganic Chemistry: A Learner Centered ApproachISBN: 9780137566471당신이 사용하는 게 아니라요?교과서 변경
3장, 문제 9d

What is the conjugate base of each of the following acids? [The most acidic proton is indicated.]
(d) Chemical structure of a phenol with an arrow indicating the most acidic proton at the hydroxyl group (OH).

검증된 단계별 안내
1
Identify the acidic proton in the molecule. In this case, the blue arrow points to the hydrogen atom attached to the oxygen in the hydroxyl (-OH) group.
Recall that the conjugate base is formed by removing the most acidic proton from the molecule. This involves deprotonation of the hydroxyl group.
Write the chemical equation for the deprotonation process: \( \text{R-OH} \rightarrow \text{R-O}^- + \text{H}^+ \), where \( \text{R} \) represents the cyclohexyl group.
Recognize that the conjugate base of the acid is the cyclohexoxide ion (\( \text{R-O}^- \)), which is the cyclohexyl group bonded to an oxygen atom carrying a negative charge.
Ensure that the negative charge on the oxygen is properly represented, as it results from the loss of the proton during deprotonation.

비슷한 문제에 대한 검증된 영상 답변:

이 영상 해법은 위 문제에 도움이 된다고 튜터들이 추천한 것입니다.
영상 길이:
3m

주요 개념

질문에 올바르게 답하기 위해 반드시 이해해야 하는 핵심 개념들은 다음과 같습니다.

Acid-Base Chemistry

Acid-base chemistry involves the transfer of protons (H+) between species. An acid is defined as a proton donor, while a base is a proton acceptor. Understanding this concept is crucial for identifying conjugate acid-base pairs, where the conjugate base is formed when an acid donates a proton.
추천 영상:
02:49
The Lewis definition of acids and bases.

Conjugate Base

The conjugate base of an acid is what remains after the acid has donated a proton. For example, when phenol (C6H5OH) donates its acidic proton from the hydroxyl group, it forms the phenoxide ion (C6H5O-), which is its conjugate base. Recognizing the structure of the conjugate base is essential for predicting its reactivity and properties.
추천 영상:
03:27
Conjugated states

Resonance Stabilization

Resonance stabilization refers to the delocalization of electrons across multiple atoms in a molecule, which can enhance stability. In the case of phenoxide ion, the negative charge on the oxygen can be delocalized into the aromatic ring, making the conjugate base more stable than if the charge were localized. This concept is important for understanding the acidity of phenols compared to other alcohols.
추천 영상:
03:43
The radical stability trend.