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Ch. 21 - Carboxylic Acid Derivatives
Wade - Organic Chemistry 9th Edition
Wade9th EditionOrganic ChemistryISBN: 9780135213728당신이 사용하는 게 아니라요?교과서 변경
21장, 문제 47b

Predict the products of saponification of the following esters.
(b)

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Step 1: Understand the concept of saponification. Saponification is a chemical reaction in which an ester reacts with a strong base (usually NaOH or KOH) to produce a carboxylate salt and an alcohol.
Step 2: Identify the ester in the given structure. The ester provided is ethyl propanoate, which consists of a propanoate group (CH3CH2CO-) and an ethoxy group (-OCH2CH3).
Step 3: Write the general reaction for saponification. The ester reacts with a strong base (e.g., NaOH) to form a carboxylate salt and an alcohol. The reaction can be represented as: R-COOR'+NaOH→R-COONa+R'OH
Step 4: Apply the reaction to the given ester. In this case, the propanoate group (CH3CH2CO-) will form the carboxylate salt (CH3CH2COO-Na+), and the ethoxy group (-OCH2CH3) will form ethanol (CH3CH2OH).
Step 5: Summarize the products. The saponification of ethyl propanoate will yield sodium propanoate (CH3CH2COO-Na+) and ethanol (CH3CH2OH).

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주요 개념

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Saponification

Saponification is a chemical reaction that involves the hydrolysis of an ester in the presence of a strong base, typically sodium hydroxide (NaOH) or potassium hydroxide (KOH). This process results in the formation of an alcohol and a carboxylate salt, which is commonly known as soap. Understanding this reaction is crucial for predicting the products when esters undergo saponification.
추천 영상:
03:27
Mechanism

Esters

Esters are organic compounds formed from the reaction of an alcohol and a carboxylic acid, characterized by the functional group -COO-. They often have distinctive odors and are commonly found in fats, oils, and natural fragrances. Recognizing the structure of esters is essential for predicting the products of their reactions, including saponification.
추천 영상:
02:39
Ester Nomenclature

Hydrolysis

Hydrolysis is a chemical process in which water is used to break down a compound. In the context of saponification, hydrolysis refers to the reaction of the ester with water, facilitated by a base, leading to the formation of an alcohol and a carboxylate ion. This concept is fundamental to understanding how esters are converted into their respective products during saponification.
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가이드 코스
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Hydrolysis of Thioesters Concept 2