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Analytical Chemistry
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Electrochemical Cells definitions
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Galvanic Cell
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Galvanic Cell
A spontaneous system generating electricity via oxidation at a negative electrode and reduction at a positive electrode, connected by a salt bridge.
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이 집합의 용어 (15)
하이드의 정의
Galvanic Cell
A spontaneous system generating electricity via oxidation at a negative electrode and reduction at a positive electrode, connected by a salt bridge.
Electrolytic Cell
A non-spontaneous system requiring external power to drive electron flow, with forced oxidation and reduction at its electrodes.
Anode
The electrode where oxidation occurs, electrons are lost, and mass decreases during cell operation.
Cathode
The electrode where reduction occurs, electrons are gained, and mass increases as ions deposit.
Salt Bridge
A tube containing neutral ions that completes the circuit by allowing ion flow between cell compartments.
Standard Cell Potential
A measure of the cell's ability to drive electron flow, with higher values favoring reduction and strong oxidizing agents.
Oxidizing Agent
A substance that gains electrons in a reaction, promoting reduction at the cathode.
Reducing Agent
A substance that loses electrons in a reaction, promoting oxidation at the anode.
Line Notation
A symbolic method using vertical lines to represent phase boundaries and salt bridges, summarizing cell components and reactions.
Half Reaction
A representation of either oxidation or reduction, showing electron transfer at a single electrode.
Gibbs Free Energy
A thermodynamic variable indicating reaction spontaneity; negative values correspond to spontaneous cell operation.
Equilibrium Constant
A value relating product and reactant concentrations at equilibrium, used to predict cell spontaneity.
Reaction Quotient
A ratio of current concentrations to equilibrium values, indicating the cell's progress toward equilibrium.
Standard Entropy
A measure of disorder under standard conditions, influencing the spontaneity and direction of cell reactions.
Phase Boundary
A separation between different physical states or oxidation states, represented by a single line in cell notation.