Understand that plant cell walls are a structural component that provides support and protection to the cell.
Recognize that the primary component of plant cell walls is a carbohydrate polymer.
Identify the four options given: Chitin, Keratin, Cellulose, and Glycogen.
Recall that cellulose is a polysaccharide consisting of a linear chain of glucose molecules, which is the main structural component of plant cell walls.
Conclude that cellulose is the correct answer, as it is the primary substance that makes up plant cell walls, unlike chitin, keratin, or glycogen.