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General Biology: Chemical Basis of Life

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  • Basic atomic structure

    Atoms consist of a nucleus containing protons (positive charge) and neutrons (neutral), surrounded by electrons (negative charge).

  • Atomic number

    The number of protons in an atom's nucleus, written as a subscript to the left of the element symbol.

  • Mass number

    The sum of protons and neutrons in an atom's nucleus.

  • Isotopes

    Atoms of the same element with different numbers of neutrons, e.g., Carbon-12, Carbon-13, Carbon-14.

  • Atomic weight

    The average mass of all naturally occurring isotopes of an element, weighted by abundance.

  • Electron shells and valence electrons

    Electrons occupy orbitals grouped into shells; the outermost shell is the valence shell containing valence electrons important for bonding.

  • Covalent bond

    A chemical bond formed when two atoms share unpaired valence electrons, creating a stable molecule.

  • Nonpolar vs. polar covalent bonds

    Nonpolar covalent bonds share electrons equally; polar covalent bonds share electrons unequally, creating partial charges.

  • Electronegativity trend

    Electronegativity increases up and to the right on the periodic table (O > N > S, C, H, P).

  • Ionic bond

    Bond formed by complete transfer of electrons from one atom to another, creating ions.

  • Cation and anion

    Cation: positively charged ion (loses electron). Anion: negatively charged ion (gains electron).

  • Molecular geometry examples

    Shapes affect molecule behavior: methane is tetrahedral, water is bent, carbon dioxide is linear.

  • Water polarity

    Water is small, bent, and highly polar due to polar covalent bonds; oxygen has partial negative charge, hydrogens partial positive.

  • Hydrogen bonding in water

    Water molecules form hydrogen bonds with each other and with polar solutes, enabling solvent properties.

  • Hydrophilic vs. hydrophobic molecules

    Hydrophilic molecules dissolve in water due to polarity; hydrophobic molecules are nonpolar and cluster together, avoiding water.

  • Cohesion, adhesion, and surface tension

    Cohesion: attraction between water molecules; adhesion: attraction to other substances; surface tension: cohesive force at water's surface.

  • Water density and ice

    Water is denser as a liquid than as a solid because ice has an open crystal structure, causing ice to float.

  • Water's heat capacity

    Water has a high specific heat due to hydrogen bonding, requiring much energy to change temperature.

  • Acids and bases in water

    Acids donate protons (increase H+), bases accept protons (decrease H+), and buffers minimize pH changes.

  • pH scale

    Measures hydrogen ion concentration: acidic < 7, neutral = 7, basic > 7; scale is logarithmic.