Understand what a buffer solution is: A buffer solution is a system that resists changes in pH when small amounts of acid or base are added. It typically consists of a weak acid and its conjugate base, or a weak base and its conjugate acid.
Identify the components of each pair: For each given pair, determine if they consist of a weak acid and its conjugate base or a weak base and its conjugate acid.
Analyze the pair HC2H3O2 / NH3: HC2H3O2 is acetic acid (a weak acid), and NH3 is ammonia (a weak base). This pair does not form a buffer because it does not consist of a weak acid and its conjugate base or a weak base and its conjugate acid.
Analyze the pair NH3 / NaCl: NH3 is a weak base, but NaCl is a salt that does not provide a conjugate acid or base. This pair does not form a buffer.
Analyze the pair HF / KF: HF is a weak acid, and KF is a salt that provides the conjugate base F-. This pair forms a buffer because it consists of a weak acid and its conjugate base.