Which of the following sets of quantum numbers is NOT allowed for an electron in an atom?
A
n = 2, l = 1, m_l = 0, m_s = +1
B
n = 1, l = 0, m_l = 0, m_s = +1/2
C
n = 3, l = 2, m_l = -2, m_s = -1/2
D
n = 4, l = 3, m_l = +2, m_s = -1/2
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1
Recall the allowed ranges for each quantum number: the principal quantum number \(n\) must be a positive integer (\(n = 1, 2, 3, \ldots\)).
The azimuthal quantum number \(l\) can take integer values from \(0\) up to \(n-1\) for a given \(n\), i.e., \(l = 0, 1, 2, \ldots, n-1\).
The magnetic quantum number \(m_l\) can take integer values from \(-l\) to \(+l\), including zero, i.e., \(m_l = -l, -(l-1), \ldots, 0, \ldots, (l-1), l\).
The spin quantum number \(m_s\) can only be \(+\frac{1}{2}\) or \(-\frac{1}{2}\).
Check each set of quantum numbers against these rules. For example, verify if \(m_s = +1\) is allowed (it is not, since \(m_s\) must be \(\pm \frac{1}{2}\)), and confirm that \(l\) is less than \(n\) in each case.