Skip to main content
Ch.6 - Electronic Structure of Atoms
Brown - Chemistry: The Central Science 14th Edition
Brown14th EditionChemistry: The Central ScienceISBN: 9780134414232당신이 사용하는 게 아니라요?교과서 변경
6장, 문제 8b

Consider a fictitious one-dimensional system with one electron. The wave function for the electron, drawn below, is c1x2 = sin x from x = 0 to x = 2p. (b) At what value or values of x will there be the greatest probability of finding the electron?
Graph of the wave function sin(x) for an electron from 0 to 2π, showing peaks and nodes.

검증된 단계별 안내
1
Identify the wave function given: \( \psi(x) = \sin(x) \) for \( x \) ranging from 0 to 2\(\pi\).
Recall that the probability density function is given by the square of the wave function: \( |\psi(x)|^2 = (\sin(x))^2 \).
Determine the values of \( x \) where \( (\sin(x))^2 \) is maximized. Since \( \sin(x) \) ranges from -1 to 1, the maximum value of \( (\sin(x))^2 \) is 1.
Find the values of \( x \) where \( \sin(x) = \pm 1 \). These occur at \( x = \frac{\pi}{2} \) and \( x = \frac{3\pi}{2} \) within the given range.
Conclude that the greatest probability of finding the electron is at \( x = \frac{\pi}{2} \) and \( x = \frac{3\pi}{2} \).

비슷한 문제에 대한 검증된 영상 답변:

이 영상 해법은 위 문제에 도움이 된다고 튜터들이 추천한 것입니다.
영상 길이:
3m
도움이 되었나요?

주요 개념

질문에 올바르게 답하기 위해 반드시 이해해야 하는 핵심 개념들은 다음과 같습니다.

Wave Function

The wave function is a mathematical description of the quantum state of a system, representing the probability amplitude of finding a particle in a given position. In this case, the wave function is given as sin(x), which describes the behavior of the electron in a one-dimensional system. The square of the wave function's magnitude gives the probability density, indicating where the electron is likely to be found.
추천 영상:
가이드 코스
03:37
Logarithmic Functions

Probability Density

Probability density is derived from the wave function and indicates the likelihood of finding a particle in a specific region of space. For a wave function ψ(x), the probability density is given by |ψ(x)|². In the context of the provided wave function sin(x), the peaks of the graph correspond to higher probabilities of locating the electron, while the nodes (where the function crosses zero) indicate positions where the electron cannot be found.
추천 영상:
가이드 코스
01:56
Density Concepts

Nodes and Antinodes

In wave mechanics, nodes are points where the wave function is zero, resulting in zero probability of finding the particle, while antinodes are points where the wave function reaches its maximum value, indicating the highest probability of finding the particle. In the graph of sin(x), the peaks represent antinodes, where the electron is most likely to be found, while the points where the function crosses the x-axis are nodes, indicating locations of zero probability.
추천 영상:
가이드 코스
01:04
Radial and Angular Nodes
관련 실천
교과서 질문

The accompanying drawing shows a contour plot for a dyz orbital. Consider the quantum numbers that could potentially correspond to this orbital. (b) What is the value of the angular momentum quantum number, l?

487
views
교과서 질문

Consider the three electronic transitions in a hydrogen atom shown here, labeled A, B, and C. (c) Calculate the wavelength of the photon emitted for each transition. Do any of these transitions lead to the emission of visible light? If so which one(s)?

Calculate the wavelength of the photon emitted for transition B.

969
views
교과서 질문

Consider the three electronic transitions in a hydrogen atom shown here, labeled A, B, and C. (b) Calculate the energy of the photon emitted for each transition.

Calculate the energy of the photon emitted for transition C.

413
views
교과서 질문

The contour representation of one of the orbitals for the n = 3 shell of a hydrogen atom is shown here. (a) What is the quantum number l for this orbital?

448
views
교과서 질문

Consider the three electronic transitions in a hydrogen atom shown here, labeled A, B, and C. (a) Three electromagnetic waves, all drawn on the same scale, are also shown. Each corresponds to one of the transitions. Which electromagnetic wave (i), (ii), or (iii), is associated with electronic transition C?

1397
views
2
rank
교과서 질문

The contour representation of one of the orbitals for the n = 3 shell of a hydrogen atom is shown here. (c) In which of the following ways would you modify this sketch if the value of the magnetic quantum number, ml, were to change? (i) It would be drawn larger, (ii) the number of lobes would change, (iii) the lobes of the orbital would point in a different direction, (iv) there would be no change in the sketch.

209
views