Skip to main content
Ch.10 - Gases
Brown - Chemistry: The Central Science 14th Edition
Brown14th EditionChemistry: The Central ScienceISBN: 9780134414232당신이 사용하는 게 아니라요?교과서 변경
모든 교과서Brown 14th EditionCh.10 - Gases문제 53
10장, 문제 53

In the Dumas-bulb technique for determining the molar mass of an unknown liquid, you vaporize the sample of a liquid that boils below 100 °C in a boiling-water bath and determine the mass of vapor required to fill the bulb. From the following data, calculate the molar mass of the unknown liquid: mass of unknown vapor, 1.012 g; volume of bulb, 354 cm3; pressure, 98.93 kPa; temperature, 99 °C.

검증된 단계별 안내
1
Convert the temperature from Celsius to Kelvin by adding 273.15 to the given temperature in Celsius.
Convert the volume from cm³ to liters by dividing the volume in cm³ by 1000.
Use the ideal gas law equation, PV = nRT, to solve for the number of moles (n) of the vapor. Here, P is the pressure in kPa, V is the volume in liters, R is the ideal gas constant (8.314 L·kPa/mol·K), and T is the temperature in Kelvin.
Rearrange the ideal gas law equation to solve for n: n = PV / RT.
Calculate the molar mass of the unknown liquid by dividing the mass of the vapor by the number of moles calculated in the previous step.

비슷한 문제에 대한 검증된 영상 답변:

이 영상 해법은 위 문제에 도움이 된다고 튜터들이 추천한 것입니다.
영상 길이:
5m

주요 개념

질문에 올바르게 답하기 위해 반드시 이해해야 하는 핵심 개념들은 다음과 같습니다.

Ideal Gas Law

The Ideal Gas Law relates the pressure, volume, temperature, and number of moles of a gas through the equation PV = nRT. In this context, it allows us to calculate the number of moles of vapor produced from the known pressure, volume, and temperature, which is essential for determining the molar mass of the unknown liquid.
추천 영상:
가이드 코스
01:15
Ideal Gas Law Formula

Molar Mass Calculation

Molar mass is defined as the mass of one mole of a substance, typically expressed in grams per mole (g/mol). To find the molar mass of the unknown liquid, we use the formula: Molar Mass = mass of vapor (g) / moles of vapor (mol), where moles are derived from the Ideal Gas Law.
추천 영상:
가이드 코스
03:12
Molar Mass Calculation Example

Vaporization and Boiling Point

Vaporization is the process of converting a liquid into vapor, which occurs at the boiling point of the liquid. In the Dumas-bulb technique, the sample is vaporized in a boiling-water bath, ensuring that the temperature remains constant at the boiling point, which is crucial for accurate measurements of pressure and volume in the gas phase.
추천 영상:
가이드 코스
03:05
Boiling Point Elevation
관련 실천
교과서 질문

(a) Calculate the density of NO2 gas at 0.970 atm and 35 °C.

559
views
교과서 질문
Magnesium can be used as a 'getter' in evacuated enclosures to react with the last traces of oxygen. (The magnesium is usually heated by passing an electric current through a wire or ribbon of the metal.) If an enclosure of 5.67 L has a partial pressure of O2 of 7.066 mPa at 30 °C, what mass of magnesium will react according to the following equation? 2 Mg1s2 + O21g2¡2 MgO1s2
550
views
교과서 질문
The molar mass of a volatile substance was determined by the Dumas-bulb method described in Exercise 10.53. The unknown vapor had a mass of 2.55 g; the volume of the bulb was 500 mL, pressure 101.33 kPa, and temperature 37 °C.Calculate the molar mass of the unknown vapor.
1064
views
교과서 질문
(b) Calculate the molar mass of a vapor that has a density of 7.135 g>L at 12 °C and 99.06 kPa.
1066
views
교과서 질문

(b) Calculate the molar mass of a gas if 2.50 g occupies 0.875 L at 685 torr and 35 °C

977
views
교과서 질문
Calcium hydride, CaH2, reacts with water to form hydrogen gas: CaH21s2 + 2 H2O1l2¡Ca1OH221aq2 + 2 H21g2 This reaction is sometimes used to inflate life rafts, weather balloons, and the like, when a simple, compact means of generating H2 is desired. How many grams of CaH2 are needed to generate 145 L of H2 gas if the pressure of H2 is 110 kPa at 21 °C?
4120
views