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Ch.17 - Additional Aspects of Aqueous Equilibria
Brown - Chemistry: The Central Science 14th Edition
Brown14th EditionChemistry: The Central ScienceISBN: 9780134414232당신이 사용하는 게 아니라요?교과서 변경
17장, 문제 64

For each of the following slightly soluble salts, write the net ionic equation, if any, for reaction with a strong acid: (a) MnS (b) PbF2 (c) AuCl3 (e) CuBr (d) Hg2C2O4.

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1
Identify the slightly soluble salt: Hg2C2O4 is mercury(I) oxalate.
Recognize that a strong acid will react with the anion of the salt. In this case, the oxalate ion (C2O4^2-) will react with the strong acid.
Write the dissociation equation for the slightly soluble salt: Hg2C2O4(s) ⇌ Hg2^2+(aq) + C2O4^2-(aq).
Consider the reaction of the oxalate ion with the strong acid (e.g., HCl): C2O4^2-(aq) + 2H+(aq) → H2C2O4(aq).
Combine the dissociation and the reaction with the strong acid to write the net ionic equation: Hg2C2O4(s) + 2H+(aq) → Hg2^2+(aq) + H2C2O4(aq).

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주요 개념

질문에 올바르게 답하기 위해 반드시 이해해야 하는 핵심 개념들은 다음과 같습니다.

Solubility and Slightly Soluble Salts

Solubility refers to the ability of a substance to dissolve in a solvent, typically water. Slightly soluble salts, like Hg2C2O4, do not dissolve significantly in water, leading to limited ionization. Understanding solubility is crucial for predicting how these salts will behave in reactions, particularly with acids.
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가이드 코스
00:28
Solubility Rules

Net Ionic Equations

A net ionic equation represents the actual chemical species that are involved in a reaction, excluding spectator ions that do not participate. This simplification helps to focus on the essential changes occurring during the reaction, particularly in acid-base reactions where ions exchange or react to form new products.
추천 영상:
가이드 코스
00:51
Net Ionic Equations

Acid-Base Reactions

Acid-base reactions involve the transfer of protons (H+) from an acid to a base. In the case of slightly soluble salts reacting with strong acids, the acid can often protonate the anions of the salt, leading to the formation of soluble products. Understanding this interaction is key to writing accurate net ionic equations for such reactions.
추천 영상:
가이드 코스
01:09
Acid-Base Reaction