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Ch.20 - Electrochemistry
Brown - Chemistry: The Central Science 14th Edition
Brown14th EditionChemistry: The Central ScienceISBN: 9780134414232당신이 사용하는 게 아니라요?교과서 변경
20장, 문제 20a

Indicate whether the following balanced equations involve oxidation–reduction. If they do, identify the elements that undergo changes in oxidation number. (a) 2 AgNO3(aq) + CoCl2(aq) → 2 AgCl(s) + Co(NO3)2(aq)

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Determine the oxidation states of each element in the reactants and products.
For AgNO_3, Ag is +1, N is +5, and O is -2.
For CoCl_2, Co is +2, and Cl is -1.
For AgCl, Ag is +1, and Cl is -1.
For Co(NO_3)_2, Co is +2, N is +5, and O is -2.

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Oxidation-Reduction Reactions

Oxidation-reduction (redox) reactions involve the transfer of electrons between substances, leading to changes in oxidation states. In these reactions, oxidation refers to the loss of electrons (increase in oxidation state), while reduction refers to the gain of electrons (decrease in oxidation state). Identifying whether a reaction is a redox process requires analyzing the oxidation states of the elements involved before and after the reaction.
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Oxidation and Reduction Reactions

Oxidation States

Oxidation states (or oxidation numbers) are assigned to atoms in a compound to indicate their degree of oxidation or reduction. The rules for determining oxidation states include that the oxidation state of an element in its elemental form is zero, and for monoatomic ions, it equals the charge of the ion. Understanding how to assign oxidation states is crucial for identifying which elements are oxidized or reduced in a chemical reaction.
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가이드 코스
02:42
Oxidation Numbers

Balancing Chemical Equations

Balancing chemical equations ensures that the number of atoms for each element is the same on both sides of the equation, reflecting the law of conservation of mass. In redox reactions, balancing also involves ensuring that the total charge is the same on both sides. This process may require adjusting coefficients and can help in identifying the changes in oxidation states of the elements involved.
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Balancing Chemical Equations
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교과서 질문

Indicate whether the following balanced equations involve oxidation–reduction. If they do, identify the elements that undergo changes in oxidation number. (a) PBr3(l) + 3 H2O(l) → H3PO3(aq) + 3 HBr(aq)

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Indicate whether the following balanced equations involve oxidation–reduction. If they do, identify the elements that undergo changes in oxidation number. (b) NaI(aq) + 3 HOCl(aq) → NaIO3(aq) + 3 HCl(aq) (c) 3 SO(1g) + 2 HNO3(aq) + 2 H2O(l) → 3 H2SO4(aq) + 2 NO(g)

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교과서 질문

At 900 °C, titanium tetrachloride vapor reacts with molten magnesium metal to form solid titanium metal and molten magnesium chloride. (a) Write a balanced equation for this reaction.

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교과서 질문

At 900 °C, titanium tetrachloride vapor reacts with molten magnesium metal to form solid titanium metal and molten magnesium chloride (c) Which substance is the reductant, and which is the oxidant?

교과서 질문

For each of the following balanced oxidation–reduction reactions, (i) identify the oxidation numbers for all the elements in the reactants and products and (ii) state the total number of electrons transferred in each reaction. (a) 2 MnO4-(aq) + 3 S2-(aq + 4 H2O(l) → 3 S(s) + 2 MnO2(s) + 8 OH-(aq) (b) 4 H2O2(aq) + Cl2O7(g) + 2 OH-(aq) → 2 ClO2-(aq) + 5 H2O(l) + 4 O2(g) (c) Ba2+(aq) + 2 OH-(aq) + H2O2(aq) + 2 ClO2(aq) → Ba(ClO2)2(s) + 2 H2O(l) + O2(g)

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교과서 질문

Hydrazine (N2H4) and dinitrogen tetroxide (N2O4) form a self-igniting mixture that has been used as a rocket propellant. The reaction products are N2 and H2O. (a) Write a balanced chemical equation for this reaction.