Sketch the structure of the complex in each of the following compounds and give the full compound name:
a. cis-[Co(NH₃)₄(H₂O)₂] (NO₃)₂

검증된 단계별 안내

Identify the central metal atom in the complex. In this case, it is cobalt (Co).

Determine the coordination number of the metal, which is the number of atoms directly bonded to the metal. Here, cobalt is bonded to 4 ammonia (NH3) molecules and 2 water (H2O) molecules, making the coordination number 6.

Recognize the geometry of the complex based on the coordination number. A coordination number of 6 typically leads to an octahedral geometry.

Arrange the ligands around the cobalt in a cis configuration. In an octahedral complex, cis means that the two similar ligands (in this case, the two water molecules) are adjacent to each other.

Name the compound using the rules for naming coordination complexes. Start with the names of the ligands in alphabetical order, followed by the metal with its oxidation state in Roman numerals, and finally the counter ions. For this complex, the name would be cis-tetraamminediaquacobalt(III) nitrate.

비슷한 문제에 대한 검증된 영상 답변:

이 영상 해법은 위 문제에 도움이 된다고 튜터들이 추천한 것입니다.

영상 길이:

10m

주요 개념

질문에 올바르게 답하기 위해 반드시 이해해야 하는 핵심 개념들은 다음과 같습니다.

Coordination Compounds

Coordination compounds consist of a central metal atom or ion bonded to surrounding molecules or ions known as ligands. The arrangement and type of ligands influence the properties and geometry of the complex. Understanding the nature of these interactions is crucial for sketching the structure of coordination complexes.

Ligands and Their Types

Ligands are ions or molecules that donate electron pairs to the central metal atom in a coordination complex. They can be classified as monodentate (binding through one atom) or polydentate (binding through multiple atoms). In the given compound, ammonia (NH3) acts as a monodentate ligand, while water (H2O) also serves as a ligand, affecting the overall structure and stability of the complex.

Geometric Isomerism

Geometric isomerism occurs in coordination compounds when ligands can be arranged differently around the central metal atom, leading to distinct spatial configurations. In the case of the compound provided, the 'cis' designation indicates that the ligands are adjacent to each other, which is important for accurately sketching the structure and understanding its chemical behavior.

Sketch the structure of the complex in each of the following compounds and give the full compound name:a. cis-[Co(NH3)4(H2O)2] (NO3)2