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Ch.12 - Solids and Solid-State Materials
McMurry - Chemistry 8th Edition
McMurry8th EditionChemistryISBN: 9781292336145당신이 사용하는 게 아니라요?교과서 변경
12장, 문제 22c

The following diagrams show the electron populations of the bands of MO energy levels for four different materials:
Diagrams showing MO energy levels for four materials and their conductivity changes with temperature.
. (c) Tell whether the conductivity of each material increases or decreases when the temperature increases.

검증된 단계별 안내
1
Identify the type of material based on the electron population in the bands: insulator, semiconductor, or conductor.
For each material, observe the distribution of electrons in the valence band (red) and conduction band (blue).
Recall that in conductors, the conductivity decreases with increasing temperature due to increased electron scattering.
For semiconductors, the conductivity increases with increasing temperature as more electrons gain enough energy to jump from the valence band to the conduction band.
For insulators, the conductivity remains very low and does not significantly change with temperature.

비슷한 문제에 대한 검증된 영상 답변:

이 영상 해법은 위 문제에 도움이 된다고 튜터들이 추천한 것입니다.
영상 길이:
3m

주요 개념

질문에 올바르게 답하기 위해 반드시 이해해야 하는 핵심 개념들은 다음과 같습니다.

Molecular Orbital Theory

Molecular Orbital (MO) Theory describes the behavior of electrons in molecules by combining atomic orbitals to form molecular orbitals. These orbitals can be filled with electrons and are categorized as bonding or antibonding. The arrangement of these orbitals influences the electrical properties of materials, including their conductivity.
추천 영상:
가이드 코스
03:06
Molecular Orbital Theory

Conductivity and Temperature Relationship

The conductivity of materials is often affected by temperature changes. In semiconductors, increasing temperature typically provides energy to electrons, allowing them to move from the valence band to the conduction band, thus increasing conductivity. Conversely, in some metals, increased temperature can lead to increased lattice vibrations, which may decrease conductivity.
추천 영상:
가이드 코스
03:48
Temperature vs Heat

Band Gap

The band gap is the energy difference between the valence band and the conduction band in a material. Materials with a small band gap, like semiconductors, can have their conductivity significantly affected by temperature, as thermal energy can promote electrons across the gap. In contrast, materials with a large band gap are generally insulators and show little change in conductivity with temperature.
추천 영상:
가이드 코스
03:13
Intepreting the Band of Stability