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Ch.14 - Chemical Kinetics
McMurry - Chemistry 8th Edition
McMurry8th EditionChemistryISBN: 9781292336145당신이 사용하는 게 아니라요?교과서 변경
14장, 문제 92c

Consider three reactions with different values of Ea and ΔE:
Reaction 1. Ea = 20 kJ>mol; ΔE = -60 kJ/mol
Reaction 2. Ea = 10 kJ>mol; ΔE = -20 kJ/mol
Reaction 3. Ea = 40 kJ>mol; ΔE = +15 kJ/mol
(c) Which reaction is the most endothermic, and which is the most exothermic?

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Understand the terms: 'endothermic' means the reaction absorbs energy (ΔE is positive), and 'exothermic' means the reaction releases energy (ΔE is negative).
Identify the ΔE values for each reaction: Reaction 1 has ΔE = -60 kJ/mol, Reaction 2 has ΔE = -20 kJ/mol, and Reaction 3 has ΔE = +15 kJ/mol.
Compare the ΔE values: The most exothermic reaction will have the most negative ΔE value, and the most endothermic reaction will have the most positive ΔE value.
Determine the most exothermic reaction: Look for the reaction with the largest negative ΔE value.
Determine the most endothermic reaction: Look for the reaction with the largest positive ΔE value.

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주요 개념

질문에 올바르게 답하기 위해 반드시 이해해야 하는 핵심 개념들은 다음과 같습니다.

Activation Energy (E<sub>a</sub>)

Activation energy is the minimum energy required for a chemical reaction to occur. It represents the energy barrier that reactants must overcome to transform into products. A lower activation energy indicates that a reaction can proceed more easily, while a higher activation energy suggests a slower reaction rate. Understanding E<sub>a</sub> is crucial for analyzing reaction kinetics and determining how temperature and catalysts can influence reaction rates.
추천 영상:
가이드 코스
02:02
Speed of Reactions

Enthalpy Change (ΔE)

Enthalpy change (ΔE) refers to the heat content change during a chemical reaction at constant pressure. It indicates whether a reaction is exothermic (releases heat, ΔE < 0) or endothermic (absorbs heat, ΔE > 0). The magnitude of ΔE helps in understanding the energy dynamics of the reaction, which is essential for predicting the feasibility and direction of the reaction under given conditions.
추천 영상:
가이드 코스
02:34
Enthalpy of Formation

Exothermic vs. Endothermic Reactions

Exothermic reactions release energy to the surroundings, resulting in a negative ΔE, while endothermic reactions absorb energy, leading to a positive ΔE. The classification of reactions as exothermic or endothermic is important for understanding energy flow in chemical processes. In the context of the given reactions, identifying which has the most negative ΔE indicates the most exothermic reaction, while the one with the highest positive ΔE indicates the most endothermic reaction.
추천 영상:
가이드 코스
02:30
Endothermic & Exothermic Reactions
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Reaction 2. Ea = 10 kJ>mol; ΔE = -20 kJ/mol

Reaction 3. Ea = 40 kJ>mol; ΔE = +15 kJ/mol

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