Skip to main content
Ch.23 - Organic and Biological Chemistry
McMurry - Chemistry 8th Edition
McMurry8th EditionChemistryISBN: 9781292336145당신이 사용하는 게 아니라요?교과서 변경
23장, 문제 91

There are two isomeric fat molecules whose components are glycerol, one palmitic acid, and two stearic acids (see Table 23.3). Draw the structures of both, and explain how they differ.

검증된 단계별 안내
1
Step 1: Understand the components of the fat molecules. Glycerol is a three-carbon alcohol with three hydroxyl (OH) groups. Palmitic acid is a saturated fatty acid with 16 carbon atoms, and stearic acid is a saturated fatty acid with 18 carbon atoms.
Step 2: Recognize that the fat molecules are triglycerides, which are formed by esterification of glycerol with three fatty acids. In this case, one palmitic acid and two stearic acids will be esterified with glycerol.
Step 3: Draw the structure of glycerol, which is a three-carbon chain with each carbon bonded to a hydroxyl group. This will serve as the backbone for the triglyceride.
Step 4: Attach the fatty acids to the glycerol backbone. For the first isomer, attach the palmitic acid to the first hydroxyl group of glycerol and the two stearic acids to the remaining two hydroxyl groups.
Step 5: For the second isomer, attach one stearic acid to the first hydroxyl group, the palmitic acid to the second hydroxyl group, and the other stearic acid to the third hydroxyl group. This arrangement will create a different isomeric structure.

주요 개념

질문에 올바르게 답하기 위해 반드시 이해해야 하는 핵심 개념들은 다음과 같습니다.

Isomerism

Isomerism refers to the phenomenon where two or more compounds have the same molecular formula but different structural arrangements or spatial orientations of atoms. In the context of fat molecules, isomers can differ in the arrangement of fatty acid chains around the glycerol backbone, leading to variations in physical and chemical properties.
추천 영상:
가이드 코스
2:14
Isomerism in Coordination Complexes Example

Fatty Acids

Fatty acids are carboxylic acids with long hydrocarbon chains, which can be saturated or unsaturated. In this question, palmitic acid (a saturated fatty acid) and stearic acid (also saturated) are components of the fat molecules. The arrangement of these fatty acids in relation to the glycerol molecule influences the properties of the fat, such as melting point and stability.
추천 영상:

Glycerol Structure

Glycerol is a three-carbon alcohol that serves as the backbone for triglycerides, which are the main constituents of body fat in humans and animals. The structure of glycerol allows it to form ester bonds with fatty acids, resulting in different types of triglycerides. The positioning of the fatty acids on the glycerol molecule is crucial for distinguishing between isomeric forms.
추천 영상:
가이드 코스
01:42
Resonance Structures
관련 실천