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Ch.13 - Solutions
Tro - Chemistry: A Molecular Approach 4th Edition
Tro4th EditionChemistry: A Molecular ApproachISBN: 9780134112831당신이 사용하는 게 아니라요?교과서 변경
13장, 문제 77

A glucose solution contains 55.8 g of glucose (C6H12O6) in 455 g of water. Determine the freezing point and boiling point of the solution.

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1
Identify the colligative properties involved: freezing point depression and boiling point elevation.
Calculate the molality (m) of the solution using the formula: \( m = \frac{\text{moles of solute}}{\text{kilograms of solvent}} \). First, find the moles of glucose by dividing the mass of glucose by its molar mass.
Use the freezing point depression formula: \( \Delta T_f = i \cdot K_f \cdot m \), where \( i \) is the van't Hoff factor (1 for glucose), \( K_f \) is the cryoscopic constant for water, and \( m \) is the molality.
Use the boiling point elevation formula: \( \Delta T_b = i \cdot K_b \cdot m \), where \( K_b \) is the ebullioscopic constant for water.
Determine the new freezing and boiling points by subtracting \( \Delta T_f \) from the normal freezing point of water (0°C) and adding \( \Delta T_b \) to the normal boiling point of water (100°C).

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주요 개념

질문에 올바르게 답하기 위해 반드시 이해해야 하는 핵심 개념들은 다음과 같습니다.

Colligative Properties

Colligative properties are physical properties of solutions that depend on the number of solute particles in a given amount of solvent, rather than the identity of the solute. These properties include boiling point elevation and freezing point depression, which occur when a solute is added to a solvent, affecting the solvent's phase changes.
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가이드 코스
01:26
Colligative Properties

Freezing Point Depression

Freezing point depression is a colligative property that describes the decrease in the freezing point of a solvent when a solute is dissolved in it. The extent of freezing point depression can be calculated using the formula ΔTf = i * Kf * m, where ΔTf is the change in freezing point, i is the van 't Hoff factor, Kf is the freezing point depression constant, and m is the molality of the solution.
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가이드 코스
01:59
Freezing Point Depression

Boiling Point Elevation

Boiling point elevation is another colligative property that refers to the increase in the boiling point of a solvent when a solute is added. This phenomenon can be quantified using the formula ΔTb = i * Kb * m, where ΔTb is the change in boiling point, i is the van 't Hoff factor, Kb is the boiling point elevation constant, and m is the molality of the solution.
추천 영상:
가이드 코스
03:05
Boiling Point Elevation