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Ch.11 - Chemical Bonding II: Molecular Shapes, VSEPR & MO Theory
Tro - Chemistry: A Molecular Approach 6th Edition
Tro6th EditionChemistry: A Molecular ApproachISBN: 9780137832217당신이 사용하는 게 아니라요?교과서 변경
11장, 문제 71

Consider the structure of the amino acid alanine. Indicate the hybridization about each interior atom.
Structural diagram of alanine showing atom hybridization for each interior atom.

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1
Identify the hybridization of each interior atom by counting the number of regions of electron density (bonds and lone pairs) around each atom.
For atom 1 (oxygen), there are 3 regions of electron density (2 lone pairs and 1 double bond), so the hybridization is sp2.
For atom 2 (carbon), there are 3 regions of electron density (1 double bond and 2 single bonds), so the hybridization is sp2.
For atom 3 (oxygen), there are 4 regions of electron density (2 lone pairs and 2 single bonds), so the hybridization is sp3.
For atom 4 (carbon), there are 4 regions of electron density (4 single bonds), so the hybridization is sp3.

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주요 개념

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Hybridization

Hybridization is the concept of mixing atomic orbitals to form new hybrid orbitals that can accommodate the bonding requirements of atoms in a molecule. In the case of alanine, understanding the hybridization of each interior atom helps predict the geometry and bond angles around those atoms, which is crucial for understanding the molecule's structure and reactivity.
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Amino Acids Structure

Amino acids are organic compounds that serve as the building blocks of proteins. Each amino acid has a central carbon atom (the alpha carbon) bonded to an amino group, a carboxyl group, a hydrogen atom, and a variable R group (side chain). The specific structure of alanine, with its methyl side chain, influences its properties and interactions in biological systems.
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Acids and Their Structure

Bond Angles and Molecular Geometry

Bond angles and molecular geometry are determined by the arrangement of electron pairs around a central atom, influenced by hybridization. For alanine, the hybridization of the carbon atoms leads to specific bond angles (e.g., approximately 109.5° for tetrahedral geometry) that dictate the overall shape of the molecule, affecting its function and interactions in biological contexts.
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